{"title":"303.15 K时四氯乙烯+乙酰丙酮、+丙烯腈、+苯甲醚和+四氢呋喃二元混合物的过量摩尔体积","authors":"A. Deo, M. Agrawal","doi":"10.6000/1929-5030.2014.03.02.9","DOIUrl":null,"url":null,"abstract":"Excess molar volumes have been measured by means of a dilatometer for tetrachloroethylene (TCE) +acetyl acetone, + acrylonitrile, +anisole and+ tetrahydrofuran at 303.15 K. V E m values are positive over the entire range of composition for TCEanisole and TCE – acetyl acetone and negative for TCETetrahydrofuran. For TCE – acrylontrile, V E m has been found to be negative up to x = 0.8379 and positive onward. Values of Vm E for the various systems have been fitted by the method of least squares with smoothing equation, and have been discussed from the viewpoint of the existence of specific interactions between the components.","PeriodicalId":15165,"journal":{"name":"Journal of Applied Solution Chemistry and Modeling","volume":"22 1","pages":"130-134"},"PeriodicalIF":0.0000,"publicationDate":"2014-06-05","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Excess Molar Volume of Binary Mixtures of Tetrachloroethylene + Acetylacetone, + Acrylonitrile, + Anisole and + Tetrahydrofuran at 303.15 K\",\"authors\":\"A. Deo, M. Agrawal\",\"doi\":\"10.6000/1929-5030.2014.03.02.9\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"Excess molar volumes have been measured by means of a dilatometer for tetrachloroethylene (TCE) +acetyl acetone, + acrylonitrile, +anisole and+ tetrahydrofuran at 303.15 K. V E m values are positive over the entire range of composition for TCEanisole and TCE – acetyl acetone and negative for TCETetrahydrofuran. For TCE – acrylontrile, V E m has been found to be negative up to x = 0.8379 and positive onward. Values of Vm E for the various systems have been fitted by the method of least squares with smoothing equation, and have been discussed from the viewpoint of the existence of specific interactions between the components.\",\"PeriodicalId\":15165,\"journal\":{\"name\":\"Journal of Applied Solution Chemistry and Modeling\",\"volume\":\"22 1\",\"pages\":\"130-134\"},\"PeriodicalIF\":0.0000,\"publicationDate\":\"2014-06-05\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Journal of Applied Solution Chemistry and Modeling\",\"FirstCategoryId\":\"1085\",\"ListUrlMain\":\"https://doi.org/10.6000/1929-5030.2014.03.02.9\",\"RegionNum\":0,\"RegionCategory\":null,\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"\",\"JCRName\":\"\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Journal of Applied Solution Chemistry and Modeling","FirstCategoryId":"1085","ListUrlMain":"https://doi.org/10.6000/1929-5030.2014.03.02.9","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"","JCRName":"","Score":null,"Total":0}
引用次数: 0
摘要
在303.15 K下,用膨胀计测量了四氯乙烯(TCE) +乙酰丙酮、+丙烯腈、+苯甲醚和+四氢呋喃的过量摩尔体积。在整个组成范围内,tce1和TCE -乙酰丙酮的V - E - m值为正,而tce4氢呋喃的V - E - m值为负。对于TCE -丙烯腈,V E m在x = 0.8379之前为负,之后为正。用平滑方程的最小二乘法拟合了各系统的vme值,并从各组分之间存在特定相互作用的观点进行了讨论。
Excess Molar Volume of Binary Mixtures of Tetrachloroethylene + Acetylacetone, + Acrylonitrile, + Anisole and + Tetrahydrofuran at 303.15 K
Excess molar volumes have been measured by means of a dilatometer for tetrachloroethylene (TCE) +acetyl acetone, + acrylonitrile, +anisole and+ tetrahydrofuran at 303.15 K. V E m values are positive over the entire range of composition for TCEanisole and TCE – acetyl acetone and negative for TCETetrahydrofuran. For TCE – acrylontrile, V E m has been found to be negative up to x = 0.8379 and positive onward. Values of Vm E for the various systems have been fitted by the method of least squares with smoothing equation, and have been discussed from the viewpoint of the existence of specific interactions between the components.