用废食用油在填充床塔中吸收产气中的焦油含量

Firman Asto Putro, J. Waluyo, Bahaul Fahmi Al Haq, W. Hidayat, S. H. Pranolo
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摘要

如果将产气用作燃料气体,产气中的焦油含量可能会导致发动机结皮,因此需要将其去除。本研究旨在确定填料床接触塔生产气中焦油脱除过程中的液相传质系数。该工艺以废食用油为吸收剂连续进行。这是通过在具有拉希环填料床的塔中,以一定的逆流流速,在491-940℃的温度范围内与废食用油接触作为可可豆荚壳气化产物的产气来进行的。采用比表面积分别为29.3927 m2/m3、49.7532 m2/m3、95.4113 m2/m3、96.8182 m2/m3、101.6840 m2/m3、105.0128 m2/m3的填料床物料,废油线速度为0.0229 m/s ~ 0.0827 m/s。在此基础上建立了传质系数数学模型。该模型分别适用于2.2397 ~ 8.0020、2.26.10 ~ 1.72.10 ~ 9、0.0331 ~ 0.3102的范围(As.dt)、(DL/dt.vL)和(µL / ρL.vL.dt),平均误差为9.33%。平均去焦油率为87%
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Absorption of Tar Content in Producer Gas using Used Cooking Oil in a Packed-bed Column
The tar content in producer gas may cause crusting on the engine if it is utilized as a fuel gas, thus it needs to be removed. This study aims to determine the liquid phase mass transfer coefficient in process of removing tar from producer gas in a packed-bed contactor column. This process is carried out continuously using used-cooking oil as absorbent. This was carried out by contacting the producer gas as a product of cacao pod-husk gasification at temperature range of 491-940oC at a certain counter-current flow rate with used-cooking oil in a column with a Raschig ring packing bed. The study used packed-bed materials with specific surface areas of 29.3927 m2/m3, 49.7532 m2/m3, 95.4113 m2/m3, 96.8182 m2/m3, 101.6840 m2/m3, and 105.0128 m2/m3, and with the linear velocity of used-cooking oil ranging from 0.0229 m/s to 0.0827 m/s. A mass transfer coefficient mathematical model has been constructed based on the research results. The model applies to the ranges (As.dt), (DL/dt.vL), and (µL / ρL.vL.dt) from 2.2397 to 8.0020, 2.26.10-10 to 1.72.10-9, and 0.0331 to 0.3102, respectively, with an average error of 9.33%. The average tar removed was 87%
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