废镍渣的无废处理

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摘要

本文提出了对部分企业多年经营积累的大量倾倒镍渣进行无害化处理的可能方案之一。该工艺包括使用水法和火法冶金处理,得到三种产品:硫酸铁、掺有少量铝的硅铁和硅铁冶炼渣。炉渣硬度为7-7.5莫氏,可用作喷砂磨料粉,也可作为生产高铝水泥的原料。由此产生的硫酸铁随后可以从铜、镍、镁和铝杂质中提纯,并使其达到现有的GOST成分要求。所得硅铁,其硅含量与带有铝混合物的标记硅铁FS 75相似,可用于所有现有等级的钢和铸铁的脱氧和硅合金化。在这种情况下,由消费企业参与制定的规范可以作为这种硅铁的规范性文件。在硅铁冶炼过程中获得的炉渣也可以在磨料粉生产企业的这些规范的框架内进行定义。
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Waste-free processing of waste nickel slags
The paper considers one of possible options for the waste-free processing of dumped masses of nickel slags, accumulated over the years of operation of some enterprises. This process includes the use of hydroand pyrometallurgical processing, which results in three products: iron sulfate, ferrosilicon with a small admixture of aluminum, and slag from the ferrosilicon smelting. The slag has a hardness of 7-7.5 Mohs and can be used as an abrasive powder for sandblasting, or as a raw material for production of high alumina cement. The resulting iron sulfate can subsequently be purified from the copper, nickel, magnesium, and aluminum impurities and brought to the existing GOST compositional requirements. The resulting ferrosilicon, whose silicon content is similar to that of the marked ferrosilicon FS 75 with an aluminum admixture, can be used for deoxidation and silicon alloying of all existing grades of steels and cast irons. In this case, specifications drawn up with participation of a consumer enterprise can be a regulatory document for such ferrosilicon. The slag obtained during the ferrosilicon smelting can also be defined within the framework of these specifications for the abrasive powder producing enterprises.
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