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Diagnostic features of rutile and cassiterite from heavy mineral concentrate samples, according to the IR microscopy data 根据红外显微镜数据从重矿物精矿样品中提取金红石和锡石的诊断特征
Pub Date : 2024-07-08 DOI: 10.47765/0869-5997-2024-10010
Galina Khachatryan, Natalia Anashkina
Based on the study of rutile and cassiterite grains, using Fourier transform infrared microscopy, a new method for their determination in heavy mineral concentrate samples has been developed. The natural vibrations of the crystal lattice of these minerals are predominantly inactive in the infrared spectrum, which complicates their identification. Rutile is proposed to be determined by the absorption band ~ 1062 cm-1; and cassiterite, by the lines 1059–1065, ~ 1130, 1217–1220, and 1366–1373 cm-1. The characteristic absorption bands in the region of 3200–3400 cm-1, associated with vibrations of OH defects in the crystal lattice of these minerals, have been shown to be of particular importance for the diagnosis of rutile and cassiterite. Structural hydroxyl groups in the spectra are manifested in rutile by a line at about 3279–3283 cm-1; and in cassiterite, by lines at about 3254–3259 cm-1, ~ 3343 and ~ 3377 cm-1.
在利用傅立叶变换红外显微镜对金红石和锡石晶粒进行研究的基础上,开发出了一种在重矿物精矿样品中测定它们的新方法。这些矿物晶格的自然振动在红外光谱中主要是不活跃的,这使得它们的鉴定变得复杂。金红石建议通过 ~ 1062 cm-1 的吸收带来确定;锡石则通过 1059-1065, ~ 1130, 1217-1220 和 1366-1373 cm-1 线来确定。3200-3400 cm-1 区域的特征吸收带与这些矿物晶格中羟基缺陷的振动有关,已被证明对诊断金红石和锡石特别重要。光谱中的结构羟基在金红石中表现为约 3279-3283 厘米-1 处的一条线;在锡石中则表现为约 3254-3259 厘米-1、~ 3343 和~ 3377 厘米-1 处的一条线。
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引用次数: 0
Rare earth mineralization in ores of the Gurvunur apatite-magnetite deposit (Ozerny ore cluster, Western Transbaikalia) 古尔武努尔磷灰石-磁铁矿矿床(外贝加尔西部奥泽尔采矿群)矿石中的稀土矿化现象
Pub Date : 2024-07-08 DOI: 10.47765/0869-5997-2024-10009
Aleksandra Izvekova, Bulat Damdinov, M. Rampilov
The Gurvunur apatite-magnetite deposit is located within the Ozerny ore cluster in Wes-tern Transbaikalia. A peculiarity of this object is the presence of rare-earth mineralization in the ores. The main REE concentrator minerals include monazite, allanite, apatite, and epidote. One of the main concentrators of REE is apatite, where the content of REE sum reaches 2.6 wt. %. The REE are mainly represented by light lanthanides, with La up to 1.8 wt. % and Ce up to 2.08 wt. % predominating. Monazite- (Ce) is formed in the process of apatite refining, leading to the monazite fine-grained dissemination and veinlets occurring. Epidote is found in nests and vein-like formations of skarn aggregates. The mineral mainly contains light lanthanides (La up to 5.11 wt. %, Ce up to 2.47 wt. %) and forms gradual transitions to allanite that, in its turn, is also found in the form of isolated segregations or as a part of aggregates of epidote-allanite composition. Light lanthanides with Ce up to 14.35 wt. % and La up to 9.16 wt. % pre-dominate in the allanite composition. The study of the mineral composition and distribution of REE in ores and minerals allows us to conclude that rare-earth mineralization in the ores of the Gurvunur apatite-magnetite deposit was formed as a result of skarning of the carbonate-bearing volcanogenic-sedimentary rocks, and the source of rare-earth mineralization was granodiorites of the Vitimkan intrusive suite.
古尔武努尔磷灰石-磁铁矿矿床位于外贝加尔西部的奥泽尔尼矿石群中。该矿藏的一个特点是矿石中存在稀土矿化。主要的稀土富集矿物包括独居石、阳起石、磷灰石和绿帘石。磷灰石是稀土的主要富集矿物之一,其稀土含量总和达到 2.6 wt.%。REE 主要由轻镧系元素构成,其中以 La(最高达 1.8 重量百分比)和 Ce(最高达 2.08 重量百分比)为主。独居石(Ce)是在磷灰石提炼过程中形成的,导致独居石细粒散布和细脉出现。表土存在于矽卡岩集合体的巢状和脉状构造中。该矿物主要含有轻镧系元素(La 最高含量为 5.11 wt.%,Ce 最高含量为 2.47 wt.%),并逐渐过渡到绿帘石,而绿帘石又以孤立的分离形式或作为鳞片矿-绿帘石成分集合体的一部分被发现。轻镧系元素(铈含量高达 14.35 重量%,镭含量高达 9.16 重量%)在绿帘石成分中占主导地位。通过对矿石和矿物中的矿物成分和稀土元素分布的研究,我们可以得出结论,古尔武努尔磷灰石-磁铁矿矿床矿石中的稀土矿化是由含碳酸盐的火山成因沉积岩脱壳形成的,而稀土矿化的来源是维提姆坎侵入岩群的花岗闪长岩。
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引用次数: 0
Microimpurities in pyrite of gold ore occurrences of the Manitanyrd ridge (the Polar Urals) 曼尼塔尼尔德山脊(极地乌拉尔)金矿矿点黄铁矿中的微杂质
Pub Date : 2024-07-08 DOI: 10.47765/0869-5997-2024-10007
L.I. Efanova, N.S. Kovalchuk, Tatyana Mayorova
The microelement composition was studied of pyrite, the main concentrator of gold in sulfidization zones in ore occurrences of the Manitanyrd Ridge. The ore mineralization is assigned to the gold-sulfide-quartz vein and gold-sulfide types. We determined a wide range of ore-forming elements, associated with gold in pyrite. These elements correspond to geochemical features of the late galena-chalcopyrite-sphalerite mineral assemblage of the ore process, as well as to its final stage expressed in the appearance of elements reflecting the mineralogy of gray ores and bismuth sulfosalts. Pyrites from the vein and mineralized zones, from the ores of the deposit and from the secondary lithochemical anomalies, were found to contain the same set of the gold satellite elements: Ag, Cu, Zn, Pb, As. In pyrite of the gold-sulfide-quartz veins, Au has close correlations with the main elements of the ore association. In pyrite of the mineralized zones, all the correlations between Au and the ore-forming elements are absent. The pair-wise correlation between the ore-forming elements in these zones also changes completely. It is demonstrated that the identified differences in correlations between Au and the ore-forming elements in pyrite are a criterion for assessment of the lithochemical anomalies and allow one to propose a strategy of prospecting for new ore objects in the Manitanyrd region.
对黄铁矿的微量元素组成进行了研究,黄铁矿是曼尼塔尼尔德山脊矿点硫化带中金的主要富集物。矿化被归类为金-硫化物-石英脉和金-硫化物类型。我们测定了黄铁矿中与金有关的多种成矿元素。这些元素与矿石形成过程中晚期方铅矿-黄铜矿-闪锌矿矿物组合的地球化学特征相吻合,也与矿石形成过程的最后阶段相吻合,这些元素的出现反映了灰色矿石和硫化铋矿的矿物学特征。从矿脉和矿化带、矿床矿石和次生岩石化学异常中发现的黄铁矿含有同一组金卫星元素:银、铜、锌、铅、砷。在金-硫化物-石英矿脉的黄铁矿中,金与矿石关联的主要元素密切相关。在矿化带的黄铁矿中,金与成矿元素之间不存在任何关联。这些矿化带中成矿元素之间的成对相关性也完全改变。研究表明,黄铁矿中金与成矿元素之间已确定的相关性差异是评估岩石化学异常的一个标准,并使人们能够提出在马尼塔尼尔德地区勘探新矿石的战略。
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引用次数: 0
Identification of new objects promising for porphyry molybdenum-copper mineralization when creating the State geological map 1000/3: Sheets O-55, O-56 (Northern Priokhotye, Magadan region) as an example 在绘制第 1000/3 号国家地质图时确定斑岩型钼铜矿化的新前景:以 O-55 和 O-56 号图幅(马加丹州普里奥霍特耶北部)为例
Pub Date : 2024-07-08 DOI: 10.47765/0869-5997-2024-10006
Antonina Alenicheva, Nikita Kasatkin, Yuri Yurchenko, Tatyana Zubova, Vitali Shatov, Sergei Sergeev
The Motykleisky, Chistoozerny, and Pavlovichsky new ore clusters promising for porphyry molybdenum-copper mineralization have been identified in the Magadan region due to results of creation of the State Geological Map 1000/3, sheets O-55, O-56. The porphyry-type mineralization is associated with the Priokhotsky plutonic belt of Albian-Cenomanian granitoids of the Magadan suite of the calcareous-alkaline series (K/Na <1). The granitoids are dominated by porphyritic tonalites and quartz diorites of type I magnetite series, often adakitic in composition. The mineralization is accommodated by the Jurassic-Lower Cretaceous island-arc sedimentary-volcanic formations. Relationship between the mineralization and granitoids is substantiated by the U-Pb SIMS SHRIMP and Re-Os TIMS dating. In potential ore clusters, the mineralization is manifested by extensive fi lds of hydrothermal-metasomatic alterations (propylites and quartz-sericite-pyrite metasomatites). Recommendations are given for follow-up large-scale geological survey and prospecting in the area of the potential ore clusters.
根据绘制国家地质图 1000/3,O-55、O-56 号图幅的结果,在马加丹地区发现了莫季克利斯基、奇斯托泽尼和帕夫洛维奇斯基新矿群,这些矿群有望形成斑岩型钼铜矿化。斑岩型矿化与普里奥霍茨基(Priokhotsky)岩浆岩带有关,该岩浆岩带由钙质-碱性系列(K/Na <1)的马加丹岩套阿尔卑斯-前一世纪花岗岩组成。这些花岗岩主要由斑状英安岩和 I 型磁铁矿系列的石英闪长岩组成,成分通常为赤铁矿。矿化由侏罗纪-下白垩统岛弧沉积火山岩地层容纳。U-Pb SIMS SHRIMP 和 Re-Os TIMS 测定证实了矿化与花岗岩之间的关系。在潜在的矿群中,矿化表现为广泛的热液-金属蚀变(丙铁矿和石英-闪锌矿-黄铁矿变质岩)。建议在潜在矿群区域进行后续大规模地质调查和勘探。
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引用次数: 0
Mineralogy of garnets from the Jubileinaya kimberlite pipe and Ottorzhenets kimberlite body Jubileinaya 金伯利岩管和 Ottorzhenets 金伯利岩体的石榴石矿物学
Pub Date : 2024-07-08 DOI: 10.47765/0869-5997-2024-10008
M. Milaushkin, Vladimir Mal’kovets, Anastasia Gibsher, Igor Yakovlev, Nikolai Tychkov
The article presents results of a study of the chemical composition of garnet xenocry-stals from a concentrate of the heavy fraction of kimberlites from the Yubileinaya pipe and Ottorzhenets kimberlite body. Samples from porphyry kimberlites and autolithic kimberlite breccias were taken for analysis from the Yubileinaya pipe. Significant differences are noted in the studied samples of peridotite garnets from the Yubileinaya kimberlite pipe and the Ottorzhenets body. Compared to the Yubileinaya pipe, the Ottorzhenets body exhibits a decreased amount of garnets of the harzburgite-dunite paragenesis in the composition range of Cr2O3 > 8.5 wt. % and CaO < 3 wt. %. On this basis, we assume that the Ottorzhenets body is not a displaced fragment of the Yubileinaya pipe, but belongs to a new unknown kimberlite body. We also assume that the diamond-bearing potential of the primary Ottorzhenets body is reduced compared to the Yubileinaya pipe, which is consistent with the information on the diamond con-tent, according to the data of AK ALROSA (PJSC)
文章介绍了对来自尤比利纳亚管道和奥托热内茨金伯利岩体的金伯利岩重组分浓缩物中的石榴石异晶的化学成分进行研究的结果。对来自 Yubileinaya 管的斑岩金伯利岩和自生金伯利岩碎屑岩样本进行了分析。所研究的尤比利纳亚金伯利岩管和奥托热内茨岩体橄榄岩石榴石样本存在显著差异。与 Yubileinaya 管道相比,Ottorzhenets 岩体在 Cr2O3 > 8.5 wt. % 和 CaO < 3 wt. % 的成分范围内,显示出哈兹堡岩-云英岩成因的石榴石数量减少。在此基础上,我们认为奥托热涅茨岩体不是尤比利纳亚岩管的移位碎片,而是属于一个新的未知金伯利岩体。根据 AK ALROSA(PJSC)公司的数据,我们还假设原生奥托热内茨岩体的含钻潜力比尤比利纳亚岩管要低,这与有关钻石含量的信息是一致的
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引用次数: 0
“Hidden” mineralogical-geochemical zonality revealed by the laser microanalysis of sulfides at the Kyzyk-Chadr deposit, Republic of Tyva 蒂瓦共和国 Kyzyk-Chadr 矿床硫化物激光显微分析揭示的 "隐藏 "矿物地球化学地带性
Pub Date : 2024-04-09 DOI: 10.47765/0869-5997-2024-10005
I. Starostin
A comprehensive study of the Kyzyk-Chadr porphyry copper deposit included determination of the composition and spatial distribution of trace elements in ore-forming sulfide minerals over the ore- hosting rock volume. The study was carried out using the mass spectrometric analysis with laser ablation of the analyzed material. Steady qualitative and quantitative elements of a “hidden” mineralogical and geochemical zonality have been identified, that are expressed in variations in the concentration of trace elements and their ratios in pyrites and chalcopyrites over the volume of the ore-bearing porphyry copper stockwork. The identified regularities correlate with the established centrifugal vector and concentric pattern of the mineralogical ore-metasomatic zonality of the ore deposit.
对 Kyzyk-Chadr 斑岩型铜矿床的综合研究包括确定矿石形成的硫化物矿物中微量元素在矿石寄存岩体中的组成和空间分布。研究采用质谱分析法,对分析材料进行激光烧蚀。已经确定了 "隐蔽的 "矿物学和地球化学分带的稳定定性和定量元素,这些元素表现为黄铁矿和黄铜矿中微量元素浓度的变化及其在含矿斑岩铜堆积层中的比例。已确定的规律性与矿床的离心矢量和矿石-金属矿物学带的同心模式相关联。
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引用次数: 0
Geological and isotopic reference points of the age of gold deposits of the Solovyovsky gold ore center in the Amur province 阿穆尔州索洛维约夫斯基金矿中心金矿床时代的地质和同位素参考点
Pub Date : 2024-04-08 DOI: 10.47765/0869-5997-2024-10004
Vitali Stepanov, Anton Melnikov
The data are presented on the geological and isotopic age of gold deposits of the Solovyovsky gold ore center in the Amur province, assigned to the gold-polymetallic, gold-sulfide-quartz, and goldquartz formation types. It is demonstrated that the geological and isotopic age of the most productive ore deposits of the gold-polymetallic (Berezitovoe) and gold-sulfide-quartz (Kirovskoe) types is Early Cretaceous according to geological data and Barremian (in the range of 131–125 million years) according to isotopic determinations. The geological age of poorly productive ore deposits of the gold-quartz type is difficult to determine due to the fact that the host rocks are most often represented by gneisses and crystal shales of Precambrian age. The isotopic age of formation of the Snezhninka and Zolotaya gora gold-quartz deposits is, respectively, Late Triassic (212 million years) and Late Jurassic (155 million years).
报告提供了阿穆尔州索洛维约夫斯基金矿中心金矿床的地质和同位素年龄数据,这些矿床被归类为金多金属、金硫化物石英和金石英形成类型。研究表明,根据地质数据,金多金属(Berezitovoe)和金硫化物石英(Kirovskoe)类型的高产矿床的地质和同位素年龄为早白垩世,而根据同位素测定,其地质和同位素年龄为巴雷姆世(1.31-1.25 亿年)。由于母岩多为前寒武纪的片麻岩和水晶页岩,因此很难确定金-石英型贫矿床的地质年代。Snezhninka 和 Zolotaya gora 金石英矿床的同位素形成年龄分别为晚三叠世(2.12 亿年)和晚侏罗世(1.55 亿年)。
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引用次数: 0
Potential mineral resources and multi-component use of natural and technogenic tungsten deposits of the Dzhida ore field (city of Zakamensk, Republic of Buryatia) 日达矿区(布里亚特共和国扎卡缅斯克市)天然和技术钨矿床的潜在矿产资源和多成分利用
Pub Date : 2024-04-08 DOI: 10.47765/0869-5997-2024-10002
Alexei Samsonov, Alexei Burmistrov, Afanasiy Tel’nov
The article provides an overview of published and deposited data on the geological structure, mineral and chemical composition of ores, and the ore processing technologies for the Barun-Naryn and other technogenic deposits formed during long-term exploitation of natural molybdenum and tungsten deposits of the Dzhida ore field. Based on statistical analysis of these data and on author’s laboratory analytical studies, the mineral potential of the natural and technogenic deposits of the region was appro- ximately quantitatively assessed for a wide complex of by-product components of the ores. Modern possibilities of multi-element processing of the technogenic raw materials accumulated in this area and outlook for solving the actual problems in the future are demonstrated
文章概述了有关地质结构、矿石的矿物和化学成分、巴伦-纳伦矿床以及在长期开采日达矿区天然钼和钨矿床过程中形成的其他技术矿床的矿石加工技术的已发表和已保存数据。根据对这些数据的统计分析和作者的实验室分析研究,对该地区天然矿床和技术矿床的矿产潜力进行了适当的定量评估,以确定矿石的各种副产品成分。展示了对该地区积累的技术原料进行多元素加工的现代可能性,以及解决未来实际问题的前景。
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引用次数: 0
Forecasting for new lode-placer gold objects in the southwestern ending of the Kurtushibinsky metallogenic zone, based on the digital relief analysis 根据数字地形分析预测库尔图西宾斯基成矿带西南端新的淀积金矿物
Pub Date : 2024-04-08 DOI: 10.47765/0869-5997-2024-10001
Vladimir Makarov, Nikita Babintsev, Vladimir Losev, Vladimir Mezhubovsky, Sergei Serdyuk, Maria Samorodskaya
The article provides conclusions on the history of development of the topography within the Kurtushibinsky metallogenic zone, based on compilation of maps of the vertex and base surfaces of different levels. The areas of erosion and accumulation of loose material, took place at different phases, have been distinguished. The outlines of the potentially gold-bearing Gagul River paleovalley were drawn, that was not previously identified. The prospect for gold of this paleostructure and its associated recent alluvial systems has been concluded. The sites most promising for placer gold exploration have been outlined.
文章根据不同层面的顶点和基底面地图的汇编,对库尔图西宾斯基成矿带的地形发展史做出了结论。文章区分了不同阶段的侵蚀和松散物质堆积区域。绘制了以前未发现的潜在含金加古尔河古河谷的轮廓。对这一古结构及其相关的近期冲积系统的金矿前景做出了结论。概述了最有希望进行块金勘探的地点。
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引用次数: 0
Gold-arsenic sulfide mineralization of the Kayancha area, Gorny Altai 戈尔诺-阿尔泰卡扬恰地区的金砷硫化物矿化
Pub Date : 2024-01-17 DOI: 10.47765/0869-5997-2023-10018
S. Kryazhev, S. Dvurechenskaya, Aleksey Okulov, Stepan Fedak
Gold-arsenic sulfide type mineralization has first been revealed for the Gorny Altai region. The mineralized zones associate with lamprophyre dikes and are controlled by steeply dipping faults transecting the Vendian-Cambrian terrigenous-carbonate-volcanogenic sequence. The ore bodies are localized in horizons of basic metavolcanic rocks, enclosed between limestone layers. The near-ore metasomatites are composed of the paragenesis of albite, magnesiosiderite, and sericite. The gold content is related to fine dissemination of arsenic pyrite and arsenopyrite. Gold in the primary and oxidized ores is submicroscopic and finely dispersed. The sulfur isotopic composition of the sulfides (δ34SCDT = 0 ‰) indicates an association of the mineralization with a deep-seated magmatic source. The Kokpatas gold deposit in western Uzbekistan is considered as an analogue.
戈尔诺-阿尔泰地区首次发现了金-砷硫化物型矿化。矿化带与灯塔状岩浆岩尖峰有关,并受到横贯文迪安-寒武纪地层-碳酸盐-火山成因序列的陡倾断层的控制。矿体位于基性变质火山岩的地层中,被石灰岩层所包围。近矿变质岩由白云石、菱镁矿和绢云母等副成因组成。金的含量与砷黄铁矿和砷黄铁矿的细微散布有关。原生矿石和氧化矿石中的金呈亚显微分散状态。硫化物的硫同位素组成(δ34SCDT = 0 ‰)表明矿化与深层岩浆源有关。乌兹别克斯坦西部的 Kokpatas 金矿床被认为是一个类似矿床。
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引用次数: 0
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