自扩散高温合成纳米铁氧体的磁性和抗菌研究

IF 0.4 Q4 CHEMISTRY, MULTIDISCIPLINARY Acta Chemica Iasi Pub Date : 2018-12-01 DOI:10.2478/achi-2018-0016
R. Bharamagoudar, A. S. Patil, S. Mathad, V. Kumbar, L. B. Kankanawadi
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引用次数: 7

摘要

摘要本文的主要目的是利用化学计量学(x = 0, 0.25, 0.5, 0.75和1.0)对Mn1−xZnxFe2O4进行结构分析、磁性研究和抗菌活性研究。采用混合燃料自蔓延高温合成法合成了锰锌纳米铁氧体。采用x射线衍射(XRD)对合成的Mn-Zn纳米铁氧体进行了表征,证实了其立方晶体结构,晶格常数在8.372 ~ 8.432 ao之间。随着Zn2+浓度的增加,饱和磁化强度(Ms)、剩磁强度(Mr)和磁子数(Mr/Ms)逐渐减小。饱和磁化强度的降低可以解释为,Zn2+浓度增加,A位上的铁离子相对数量减少,从而降低了A - b相互作用。进一步,对合成的Mn-Zn纳米铁氧体对革兰氏阳性菌株(金黄色葡萄球菌ATCC No- 12598、淀粉样乳杆菌ATCC No- 12598)、革兰氏阴性菌株大肠杆菌ATCC No- 25922、假单胞菌ATCC No- 25619)和一种真菌(白色念珠菌ATCC No- 2091)的抑菌活性进行了测试。
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Magnetic and Antibacterial Studies of Nanoferrites Prepared by Self Propagating High-Temperature Synthesis Route
Abstract The main objective of the manuscript is the structural analysis, magnetic investigation and antimicrobial activity of Mn1−xZnxFe2O4 with stoichiometry (x = 0, 0.25, 0.5, 0.75, and 1.0). The Mn-Zn nanoferrites were synthesized by self propagating high-temperature synthesis using a mixture of fuels. The synthesized Mn-Zn nanoferrites were characterized by X-ray diffraction (XRD) that confirms cubic crystal structure with lattice constant in the range 8.372-8.432Ao. It is observed that saturation magnetization (Ms), remanence magnetization (Mr) and magneton number (Mr/Ms) decreased gradually with the increasing of Zn2+ concentration. The decrease in the saturation magnetization may be explained as, the Zn2+ concentration increases, the relative number of ferric ions on the A sites diminishes and this reduces the A–B interaction. Further, the synthesized Mn-Zn nanoferrites were tested for antibacterial activities against two-gram positive strains (Staphylococcus aureus ATCC No–12598, Lactobacillus amylovorus ATCC No– 12598), gram-negative strains E.coli ATCC No – 25922, Pseudomonas- ATCC No- 25619) and one fungal strain (C.albicans -ATCC No – 2091).
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Acta Chemica Iasi
Acta Chemica Iasi CHEMISTRY, MULTIDISCIPLINARY-
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