圣费尔南多原油沥青质气化制合成气

IF 0.5 4区 工程技术 Q4 ENERGY & FUELS Ct&f-Ciencia Tecnologia Y Futuro Pub Date : 2009-12-31 DOI:10.29047/01225383.457
Luz Edelmira Afanador Rey, Jorge Luis Grosso Vargas, Laura Smith Moreno Arciniegas, Fabio Ernesto Rodríguez Corredor
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引用次数: 0

摘要

在这项工作中,我们在哥伦比亚开展了第一项研究,以获取和评估沥青质气化产生的合成气成分。这些沥青质来自于对San Fernando原油的脱沥青过程的实施,目的是寻找其利用的技术选择。我们在实验室规模上进行了沥青质气化设施的设计、安装和调试,它遵循实验方法,进行了九次测试,并将温度和助剂气化量(氧气)作为独立变量。用两种色谱技术对气化产生的合成气进行了分析,报告了炼厂气和硫的存在。随着温度的升高,CO、H2和硫的组成呈增长趋势,CH4和CO2的组成呈下降趋势。在每个操作温度水平下,使用不同数量的气化剂(33%,40%和47%的理论完全燃烧所需的氧气量)来评估合成气的组成。当使用40%的气化剂时,气化过程中感兴趣的气体CO和H2的平均含量更高。
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SYNGAS OBTAINMENT FROM THE GASIFICATION OF ASPHALTENES OF THE SAN FERNANDO CRUDE OIL
In this work, we developed the first study in Colombia to obtain and evaluate syngas compositions derived from asphaltenes gasification. These asphaltenes came from the implementation of a Deasphalting process to San Fernando crude oil, with the purpose of looking for technological options for their utilization. We performed the design, installation and commissioning of facilities for the gasification of asphaltenes at laboratory scale, it following an experimental methodology, performing nine tests and considering temperature and agent gasification quantity (oxygen) as independent variables. The syngas derived from gasification was analyzed by two chromato graphic techniques, which reported the presence of refinery gases and sulfur. We evidenced a growth tendency of CO, H2 and sulfur composition and a decrease in CH4 and CO2 composition with temperature. The composition of the syngas was evaluated with different quantities of gasification agent (33%, 40% and 47% the amount of oxygen theoretically required for complete combustion) at each temperature levels operated. It was established that when using a 40% of gasification agent, you get greater average content of CO and H2, which are the interest gases in the gasification process.
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来源期刊
Ct&f-Ciencia Tecnologia Y Futuro
Ct&f-Ciencia Tecnologia Y Futuro Energy-General Energy
CiteScore
1.50
自引率
0.00%
发文量
7
审稿时长
>12 weeks
期刊介绍: The objective of CT&F is to publish the achievements of scientific research and technological developments of Ecopetrol S.A. and the research of other institutions in the field of oil, gas and alternative energy sources. CT&F welcomes original, novel and high-impact contributions from all the fields in the oil and gas industry like: Acquisition and Exploration technologies, Basins characterization and modeling, Petroleum geology, Reservoir modeling, Enhanced Oil Recovery Technologies, Unconventional resources, Petroleum refining, Petrochemistry, Upgrading technologies, Technologies for fuels quality, Process modeling, and optimization, Supply chain optimization, Biofuels, Renewable energies.
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