毛利藤茎活性炭的孔隙特性及吸附性能研究

IF 0.5 Q4 CHEMISTRY, MULTIDISCIPLINARY Journal of Siberian Federal University. Chemistry Pub Date : 2021-06-01 DOI:10.17516/1998-2836-0225
A. Benhathat, M. Amrani
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引用次数: 0

摘要

本文研究了毛利塔尼蛇茎活性炭(AMSAC)的合成与表征。采用氮气吸附-解吸等温线、扫描电镜(SEM)、能量色散x射线(EDX)和傅里叶变换红外光谱(FTIR)对磷酸活化炭化法制备的活性炭进行了表征。研究了AMSAC对水中亚甲基蓝的吸附电位。实验数据发现,AMSAC的BET (brunauer - emmet - teller)表面积高达1293 m2/g,孔隙丰富,比容为1.23 m3/g。FTIR分析表明,AMSAC表面存在多种官能团,这些官能团在吸附过程中发挥重要作用。与Freundlich等温线模型相比,Langmuir等温线模型能较好地拟合蓝亚甲基的平衡数据;25℃时,AMSAC的单层吸附量为411.8 mg/g
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Pore Characteristics and Adsorption Properties of Activated Carbon Produced from Ampelodismos Mauritanicus Stems
In this paper, the synthesis and characterization of Ampelodesmos mauritanicus stems activated carbon (AMSAC) were studied. The produced activated carbon by phosphoric acid activation followed carbonisation was characterized by N2 adsorption-desorption isotherm, scanning electron microscopy (SEM), energy-dispersive X-ray (EDX) analysis, and Fourier transform infrared (FTIR) spectroscopy. Sorption potential of AMSAC for the removal of methylene bleu from water was investigated. The experimental data found that AMSAC had high Brunauer-Emmett-Teller (BET) surface area of 1293 m2/g and abundant pores with specific volume of 1.23 m3/g. FTIR analysis reveals various functional groups on the surface of AMSAC which can be play an important role for the adsorption process. Langmuir isotherm model fitted well the equilibrium data for the methylene bleu comparing to the Freundlich isotherm model; the monolayer sorption capacity of AMSAC was found to be 411.8 mg/g at 25 °C
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