{"title":"1,3,5-三氮杂-7-磷金刚烷水溶性配体的合成与表征","authors":"Anita Bhatia , Senthilkumar Muthaiah","doi":"10.1080/10426507.2022.2116639","DOIUrl":null,"url":null,"abstract":"<div><p>Four new water-soluble bidentate ligands, namely, (cyclopentadienyl)ethyl-1,3,5-triaza-7-phosphadamantane (<strong>1</strong>), 1,2-bis-(1,3,5-triaza-7-phosphaadamantan-6-yl) ethane (<strong>2</strong>), 1,3-bis-(1,3,5-triaza-7-phosphaaadamantan-6-yl) propane (<strong>3</strong>) and 1,4-bis-(1,3,5-triaza-7-phosphaadamantan-6-yl) butane (<strong>4</strong>) have been synthesized and characterized by multi-nuclear NMR (<sup>1</sup>H, <sup>13</sup>C and <sup>31</sup>P), elemental analysis and mass spectrometry. Compound <strong>1</strong> was synthesized by using two different synthetic routes in excellent yields and is also the first example of water-soluble chelating cyclopentadienyl ligand containing 1,3,5-triaza-7-phosphaadamantane.</p></div>","PeriodicalId":20056,"journal":{"name":"Phosphorus, Sulfur, and Silicon and the Related Elements","volume":"198 2","pages":"Pages 122-127"},"PeriodicalIF":1.6000,"publicationDate":"2022-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"1","resultStr":"{\"title\":\"Synthesis and characterization of 1,3,5-triaza-7-phosphaadamantane based water-soluble ligands\",\"authors\":\"Anita Bhatia , Senthilkumar Muthaiah\",\"doi\":\"10.1080/10426507.2022.2116639\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<div><p>Four new water-soluble bidentate ligands, namely, (cyclopentadienyl)ethyl-1,3,5-triaza-7-phosphadamantane (<strong>1</strong>), 1,2-bis-(1,3,5-triaza-7-phosphaadamantan-6-yl) ethane (<strong>2</strong>), 1,3-bis-(1,3,5-triaza-7-phosphaaadamantan-6-yl) propane (<strong>3</strong>) and 1,4-bis-(1,3,5-triaza-7-phosphaadamantan-6-yl) butane (<strong>4</strong>) have been synthesized and characterized by multi-nuclear NMR (<sup>1</sup>H, <sup>13</sup>C and <sup>31</sup>P), elemental analysis and mass spectrometry. Compound <strong>1</strong> was synthesized by using two different synthetic routes in excellent yields and is also the first example of water-soluble chelating cyclopentadienyl ligand containing 1,3,5-triaza-7-phosphaadamantane.</p></div>\",\"PeriodicalId\":20056,\"journal\":{\"name\":\"Phosphorus, Sulfur, and Silicon and the Related Elements\",\"volume\":\"198 2\",\"pages\":\"Pages 122-127\"},\"PeriodicalIF\":1.6000,\"publicationDate\":\"2022-01-01\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"1\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Phosphorus, Sulfur, and Silicon and the Related Elements\",\"FirstCategoryId\":\"92\",\"ListUrlMain\":\"https://www.sciencedirect.com/org/science/article/pii/S1042650723001302\",\"RegionNum\":4,\"RegionCategory\":\"化学\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"2023/2/1 0:00:00\",\"PubModel\":\"Epub\",\"JCR\":\"Q4\",\"JCRName\":\"CHEMISTRY, INORGANIC & NUCLEAR\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Phosphorus, Sulfur, and Silicon and the Related Elements","FirstCategoryId":"92","ListUrlMain":"https://www.sciencedirect.com/org/science/article/pii/S1042650723001302","RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"2023/2/1 0:00:00","PubModel":"Epub","JCR":"Q4","JCRName":"CHEMISTRY, INORGANIC & NUCLEAR","Score":null,"Total":0}
Synthesis and characterization of 1,3,5-triaza-7-phosphaadamantane based water-soluble ligands
Four new water-soluble bidentate ligands, namely, (cyclopentadienyl)ethyl-1,3,5-triaza-7-phosphadamantane (1), 1,2-bis-(1,3,5-triaza-7-phosphaadamantan-6-yl) ethane (2), 1,3-bis-(1,3,5-triaza-7-phosphaaadamantan-6-yl) propane (3) and 1,4-bis-(1,3,5-triaza-7-phosphaadamantan-6-yl) butane (4) have been synthesized and characterized by multi-nuclear NMR (1H, 13C and 31P), elemental analysis and mass spectrometry. Compound 1 was synthesized by using two different synthetic routes in excellent yields and is also the first example of water-soluble chelating cyclopentadienyl ligand containing 1,3,5-triaza-7-phosphaadamantane.
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Phosphorus, Sulfur, and Silicon and the Related Elements is a monthly publication intended to disseminate current trends and novel methods to those working in the broad and interdisciplinary field of heteroatom chemistry.
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