{"title":"1,3,5-三氮杂-7-磷金刚烷水溶性配体的合成与表征","authors":"Anita Bhatia , Senthilkumar Muthaiah","doi":"10.1080/10426507.2022.2116639","DOIUrl":null,"url":null,"abstract":"<div><p>Four new water-soluble bidentate ligands, namely, (cyclopentadienyl)ethyl-1,3,5-triaza-7-phosphadamantane (<strong>1</strong>), 1,2-bis-(1,3,5-triaza-7-phosphaadamantan-6-yl) ethane (<strong>2</strong>), 1,3-bis-(1,3,5-triaza-7-phosphaaadamantan-6-yl) propane (<strong>3</strong>) and 1,4-bis-(1,3,5-triaza-7-phosphaadamantan-6-yl) butane (<strong>4</strong>) have been synthesized and characterized by multi-nuclear NMR (<sup>1</sup>H, <sup>13</sup>C and <sup>31</sup>P), elemental analysis and mass spectrometry. Compound <strong>1</strong> was synthesized by using two different synthetic routes in excellent yields and is also the first example of water-soluble chelating cyclopentadienyl ligand containing 1,3,5-triaza-7-phosphaadamantane.</p></div>","PeriodicalId":1,"journal":{"name":"Accounts of Chemical Research","volume":null,"pages":null},"PeriodicalIF":16.4000,"publicationDate":"2022-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"1","resultStr":"{\"title\":\"Synthesis and characterization of 1,3,5-triaza-7-phosphaadamantane based water-soluble ligands\",\"authors\":\"Anita Bhatia , Senthilkumar Muthaiah\",\"doi\":\"10.1080/10426507.2022.2116639\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<div><p>Four new water-soluble bidentate ligands, namely, (cyclopentadienyl)ethyl-1,3,5-triaza-7-phosphadamantane (<strong>1</strong>), 1,2-bis-(1,3,5-triaza-7-phosphaadamantan-6-yl) ethane (<strong>2</strong>), 1,3-bis-(1,3,5-triaza-7-phosphaaadamantan-6-yl) propane (<strong>3</strong>) and 1,4-bis-(1,3,5-triaza-7-phosphaadamantan-6-yl) butane (<strong>4</strong>) have been synthesized and characterized by multi-nuclear NMR (<sup>1</sup>H, <sup>13</sup>C and <sup>31</sup>P), elemental analysis and mass spectrometry. Compound <strong>1</strong> was synthesized by using two different synthetic routes in excellent yields and is also the first example of water-soluble chelating cyclopentadienyl ligand containing 1,3,5-triaza-7-phosphaadamantane.</p></div>\",\"PeriodicalId\":1,\"journal\":{\"name\":\"Accounts of Chemical Research\",\"volume\":null,\"pages\":null},\"PeriodicalIF\":16.4000,\"publicationDate\":\"2022-01-01\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"1\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Accounts of Chemical Research\",\"FirstCategoryId\":\"92\",\"ListUrlMain\":\"https://www.sciencedirect.com/org/science/article/pii/S1042650723001302\",\"RegionNum\":1,\"RegionCategory\":\"化学\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q1\",\"JCRName\":\"CHEMISTRY, MULTIDISCIPLINARY\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Accounts of Chemical Research","FirstCategoryId":"92","ListUrlMain":"https://www.sciencedirect.com/org/science/article/pii/S1042650723001302","RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q1","JCRName":"CHEMISTRY, MULTIDISCIPLINARY","Score":null,"Total":0}
Synthesis and characterization of 1,3,5-triaza-7-phosphaadamantane based water-soluble ligands
Four new water-soluble bidentate ligands, namely, (cyclopentadienyl)ethyl-1,3,5-triaza-7-phosphadamantane (1), 1,2-bis-(1,3,5-triaza-7-phosphaadamantan-6-yl) ethane (2), 1,3-bis-(1,3,5-triaza-7-phosphaaadamantan-6-yl) propane (3) and 1,4-bis-(1,3,5-triaza-7-phosphaadamantan-6-yl) butane (4) have been synthesized and characterized by multi-nuclear NMR (1H, 13C and 31P), elemental analysis and mass spectrometry. Compound 1 was synthesized by using two different synthetic routes in excellent yields and is also the first example of water-soluble chelating cyclopentadienyl ligand containing 1,3,5-triaza-7-phosphaadamantane.
期刊介绍：
Accounts of Chemical Research presents short, concise and critical articles offering easy-to-read overviews of basic research and applications in all areas of chemistry and biochemistry. These short reviews focus on research from the author’s own laboratory and are designed to teach the reader about a research project. In addition, Accounts of Chemical Research publishes commentaries that give an informed opinion on a current research problem. Special Issues online are devoted to a single topic of unusual activity and significance.
Accounts of Chemical Research replaces the traditional article abstract with an article "Conspectus." These entries synopsize the research affording the reader a closer look at the content and significance of an article. Through this provision of a more detailed description of the article contents, the Conspectus enhances the article's discoverability by search engines and the exposure for the research.
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