一种新型功能化α-羟基膦酸锡(IV)氯化配合物的合成、晶体结构、光谱和Hirshfeld表面研究

IF 1.4 4区 化学 Q4 CHEMISTRY, INORGANIC & NUCLEAR Phosphorus, Sulfur, and Silicon and the Related Elements Pub Date : 2023-12-02 DOI:10.1080/10426507.2023.2222868
Sondes Zairi , Wafa Selmi , Haitham Elleuch , Mohamed Faouzi Zid , Farhat Rezgui
{"title":"一种新型功能化α-羟基膦酸锡(IV)氯化配合物的合成、晶体结构、光谱和Hirshfeld表面研究","authors":"Sondes Zairi ,&nbsp;Wafa Selmi ,&nbsp;Haitham Elleuch ,&nbsp;Mohamed Faouzi Zid ,&nbsp;Farhat Rezgui","doi":"10.1080/10426507.2023.2222868","DOIUrl":null,"url":null,"abstract":"<div><div>A new octahedral [SnCl<sub>4</sub>L·H<sub>2</sub>O] complex (L = γ-keto allyl phosphonate) (<strong>1</strong>) was prepared and characterized by multinuclear (<sup>1</sup>H, <sup>13</sup>C, <sup>31</sup>P, and <sup>119</sup>Sn) NMR spectroscopy, IR spectroscopy, and single-crystal X-ray diffraction. The NMR data show that, in solution, the complex exclusively exists in <em>trans</em> isomeric form. The solution structure was confirmed by <sup>119</sup>Sn NMR spectrum, showing a single triplet corresponding to the <em>trans</em> isomer. The effect of distant substituent on the metal–ligand interaction was investigated and compared to closely related tin–phosphoryl complexes. The crystal structure is stabilized by strong O-H···Cl hydrogen bonds forming layers of dimers with absence of π–π interactions. The Hirshfeld surface analysis confirms the interactions involving hydrogen atoms in the complex by the higher percentage of H···H (41.1%) and Cl···H/H···Cl (40%) interactions.</div></div>","PeriodicalId":20056,"journal":{"name":"Phosphorus, Sulfur, and Silicon and the Related Elements","volume":"198 12","pages":"Pages 1002-1008"},"PeriodicalIF":1.4000,"publicationDate":"2023-12-02","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Synthesis, crystal structure, spectroscopic, and Hirshfeld surface study of a new functionalized α-hydroxyphosphonate complex of tin(IV) chloride\",\"authors\":\"Sondes Zairi ,&nbsp;Wafa Selmi ,&nbsp;Haitham Elleuch ,&nbsp;Mohamed Faouzi Zid ,&nbsp;Farhat Rezgui\",\"doi\":\"10.1080/10426507.2023.2222868\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<div><div>A new octahedral [SnCl<sub>4</sub>L·H<sub>2</sub>O] complex (L = γ-keto allyl phosphonate) (<strong>1</strong>) was prepared and characterized by multinuclear (<sup>1</sup>H, <sup>13</sup>C, <sup>31</sup>P, and <sup>119</sup>Sn) NMR spectroscopy, IR spectroscopy, and single-crystal X-ray diffraction. The NMR data show that, in solution, the complex exclusively exists in <em>trans</em> isomeric form. The solution structure was confirmed by <sup>119</sup>Sn NMR spectrum, showing a single triplet corresponding to the <em>trans</em> isomer. The effect of distant substituent on the metal–ligand interaction was investigated and compared to closely related tin–phosphoryl complexes. The crystal structure is stabilized by strong O-H···Cl hydrogen bonds forming layers of dimers with absence of π–π interactions. The Hirshfeld surface analysis confirms the interactions involving hydrogen atoms in the complex by the higher percentage of H···H (41.1%) and Cl···H/H···Cl (40%) interactions.</div></div>\",\"PeriodicalId\":20056,\"journal\":{\"name\":\"Phosphorus, Sulfur, and Silicon and the Related Elements\",\"volume\":\"198 12\",\"pages\":\"Pages 1002-1008\"},\"PeriodicalIF\":1.4000,\"publicationDate\":\"2023-12-02\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Phosphorus, Sulfur, and Silicon and the Related Elements\",\"FirstCategoryId\":\"92\",\"ListUrlMain\":\"https://www.sciencedirect.com/org/science/article/pii/S1042650723002216\",\"RegionNum\":4,\"RegionCategory\":\"化学\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q4\",\"JCRName\":\"CHEMISTRY, INORGANIC & NUCLEAR\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Phosphorus, Sulfur, and Silicon and the Related Elements","FirstCategoryId":"92","ListUrlMain":"https://www.sciencedirect.com/org/science/article/pii/S1042650723002216","RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q4","JCRName":"CHEMISTRY, INORGANIC & NUCLEAR","Score":null,"Total":0}
引用次数: 0

摘要图片

查看原文
分享 分享
微信好友 朋友圈 QQ好友 复制链接
本刊更多论文
Synthesis, crystal structure, spectroscopic, and Hirshfeld surface study of a new functionalized α-hydroxyphosphonate complex of tin(IV) chloride
A new octahedral [SnCl4L·H2O] complex (L = γ-keto allyl phosphonate) (1) was prepared and characterized by multinuclear (1H, 13C, 31P, and 119Sn) NMR spectroscopy, IR spectroscopy, and single-crystal X-ray diffraction. The NMR data show that, in solution, the complex exclusively exists in trans isomeric form. The solution structure was confirmed by 119Sn NMR spectrum, showing a single triplet corresponding to the trans isomer. The effect of distant substituent on the metal–ligand interaction was investigated and compared to closely related tin–phosphoryl complexes. The crystal structure is stabilized by strong O-H···Cl hydrogen bonds forming layers of dimers with absence of π–π interactions. The Hirshfeld surface analysis confirms the interactions involving hydrogen atoms in the complex by the higher percentage of H···H (41.1%) and Cl···H/H···Cl (40%) interactions.
求助全文
通过发布文献求助,成功后即可免费获取论文全文。 去求助
来源期刊
CiteScore
2.60
自引率
7.70%
发文量
103
审稿时长
2.1 months
期刊介绍: Phosphorus, Sulfur, and Silicon and the Related Elements is a monthly publication intended to disseminate current trends and novel methods to those working in the broad and interdisciplinary field of heteroatom chemistry.
期刊最新文献
Synthesis and characterization of diphenylether-based oxime ligands containing unilaterally substituted 1,3,4-thiadiazole groups and investigation of their some transition metal complexes Synthesis and antimicrobial evaluation of new quinazolinone derivatives containing thiourea and thiazolidine moieties Synthesis, crystal structure and evaluation of antibacterial activity of new hybrid systems containing furan-2-one and chromen-4-thione fragments Review on the synthesis of thiourea-triazine hybrid derivatives and its applications primarily in biological context On carbon nanocones CNCm[n] and their face index
×
引用
GB/T 7714-2015
复制
MLA
复制
APA
复制
导出至
BibTeX EndNote RefMan NoteFirst NoteExpress
×
×
提示
您的信息不完整,为了账户安全,请先补充。
现在去补充
×
提示
您因"违规操作"
具体请查看互助需知
我知道了
×
提示
现在去查看 取消
×
提示
确定
0
微信
客服QQ
Book学术公众号 扫码关注我们
反馈
×
意见反馈
请填写您的意见或建议
请填写您的手机或邮箱
已复制链接
已复制链接
快去分享给好友吧!
我知道了
×
扫码分享
扫码分享
Book学术官方微信
Book学术文献互助
Book学术文献互助群
群 号:481959085
Book学术
文献互助 智能选刊 最新文献 互助须知 联系我们:info@booksci.cn
Book学术提供免费学术资源搜索服务,方便国内外学者检索中英文文献。致力于提供最便捷和优质的服务体验。
Copyright © 2023 Book学术 All rights reserved.
ghs 京公网安备 11010802042870号 京ICP备2023020795号-1