烟酸镍与某些酸性酰胺的配位化合物

M. Ibragimova
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引用次数: 1

摘要

本文合成了烟酸镍与某些酸性酰胺的配合物,目的是改变烟酸基与乙醯胺、碳醯胺、硫醯胺和烟酰胺的配位所得到的化合物的组成和单个性质。通过振动光谱和热分析对有机配体的配位、中心离子的环境和合成化合物的热行为进行了表征。对合成的配合物与烟酸镍的相对强度和空间结构进行对比分析,发现新合成的配合物与原有的配合物不同,因为它们具有独立的晶格。合成的化合物的漫反射电子光谱表明,二价镍的配位化合物具有八面体的几何结构。实验证明,所合成的化合物可作为棉花生长促进剂。
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Coordination Compounds of Nickel - Nicotinate with Some Acid Amides
Complexes of Nickel - Nicotinate with some acid amides are synthesized aiming to vary the composition and the individual properties of the compounds obtained through coordination of the nicotinate group to aceta mide, carbomide, thiocarbomide and nicotinamide. The coordination of the organic ligands, the environment of the central ion and thermal behavior of the synthesized compounds are elucidated by vibrational spectroscopy and thermal analysis. The comparative consideration of the relative intensities and the spatial structures of Nickel - Nicotinate, and the complexes synthesized shows that the new coordination compounds differ from each other and the original components as they have individual crystal lattices. Electronic spectra of the diffuse reflection of the synthesized compounds have shown that coordination compounds of divalent Nickel have an octahedral geometry. It is experimentally verified that the compounds synthesized can be used as cotton growth stimu lators.
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