多功能储能复合材料的机电性能研究

Anthony Bombik, Sung Yeon Sara Ha, A. Nasrollahi, M. Haider, F. Chang
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摘要

多功能储能复合材料(MESC)是一种复合夹层结构,将电池堆层置于两层CFRP之间,并用低密度聚乙烯(LDPE)密封,形成统一的材料。由于层状锂离子堆具有可忽略不计的平面外剪切刚度,因此电池两侧的两块CFRP片材使用LDPE铆钉连接,铆钉通过在电池层上切割的孔。铆钉的剪切传递机制大大提高了MESC的剪切刚度和强度。作为编制MESC设计指南的第一步,通过实验研究了MESC的高耦合力学和电学行为。几个MESC细胞在三点弯曲载荷下进行了测试。测量了MESC的载荷、变形和电势,并观察了其电气和机械故障。建立了模拟MESC中电化学-力学耦合效应的有限元模型。在此模型中,提出了一种新的电池材料本构关系,并通过实验结果进行了验证。该模型可用于模拟具有不同结构和材料特性的MESCs,为MESCs在多种应用中的设计提供指导。
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Mechanical-Electrical Behavior of Multifunctional Energy Storage Composites
Multi-functional Energy Storage Composites (MESC) are composite sandwich structures where battery stack layers are placed between two layers of CFRP and sealed by low-density polyethylene (LDPE), forming a unified material. Because the layered Li-ion stacks have negligible out-of-plain shear stiffness, the two CFRP sheets on both sides of the battery are connected using LDPE rivets that pass through holes cut through the battery layers. The shear transfer mechanism of the rivets substantially enhances the shear stiffness and strength of the MESC. As the first step of preparing a guide for MESC design, the highly coupled mechanical and electrical behavior of MESC was studied through experiments. Several MESC cells were tested under three-point-bending loads. The load, deformation, and electric potential of the MESC were measured, and the electrical and mechanical failures were observed. A finite element model was developed to simulate the electro-chemo-mechanical coupling effect in MESC. In this model, a new constitutive relation of the battery material is proposed and verified by the experimental results. The resulting model can be used to simulate MESCs with various configurations and material properties to provide a design guideline of MESCs in multiple applications.
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