热塑性塑料中用作抗菌剂的有机添加剂

D. Tomacheski, M. Pittol, V. Ribeiro, R. Santana
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引用次数: 0

摘要

开发具有抗菌特性的聚合物可以避免变质,并有助于遏制对人类健康有害的病原体的传播。本研究旨在比较含有有机抗菌添加剂的聚合物基质的抗菌性能和力学性能。在热塑性弹性体配方中,以2%的比例对银改性膨润土(ag_膨润土)和基于母粒的聚乙烯(Cl_PE)中的有机氯分子进行了测试。采用熔融混合法制备了聚合物基质,并对金黄色葡萄球菌(S. aureus)和大肠杆菌(E. coli)菌株的拉伸性能和抗菌性能进行了评价。通过热重分析(TGA)和扫描电镜(SEM)对添加剂进行了表征。通过扫描电镜对ag_膨润土的纳米级进行了验证。TGA分析表明,Cl_PE比ag_膨润土对热更敏感。由于这种较低的热稳定性,Cl_PE的加入降低了化合物的拉伸性能。含Cl_PE的样品对两种细菌均有效,金黄色葡萄球菌和大肠杆菌的数量分别减少99%和96%。添加ag_膨润土对金黄色葡萄球菌和大肠杆菌的抗拉强度没有影响,分别降低了97%和40%。结果表明,有机添加剂的使用是有希望的,但在加工过程中必须进一步改进。
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Organic additives as antimicrobial agents in thermoplastics compounds
Development of polymers with antimicrobial characteristics can avoid deterioration and assist in containing spread of pathogens harmful to human health. This study aimed to compare the antimicrobial and mechanical properties of polymeric matrices containing organic antimicrobial additives. Silver organomodified bentonite (Ag_bentonite) and organochlorine molecule in a masterbatch based polyethylene (Cl_PE) were tested in proportion of 2% in a thermoplastic elastomeric formulation. The polymeric matrices were prepared by melt mixing and evaluated in tensile and antimicrobial properties against Staphylococcus aureus ( S. aureus ) and Escherichia coli ( E. coli) strains . The additives were characterized by thermogravimetric analysis (TGA) and scanning electron microscopy (SEM). The nanoscale of Ag_bentonite was verified by SEM. TGA assay showed that Cl_PE is more sensitive to heat than Ag_bentonite. As a result of this lower thermal stability, the addition of Cl_PE reduced the tensile properties of the compound. The sample with Cl_PE was effective against both bacterial strains, reducing the populations of S. aureus and E. coli in 99 and 96%, respectively. The addition of Ag_bentonite did not affect the tensile strength and decreased in 97 and 40% S. aureus and E. coli populations, respectively. The results indicate that the use of organic additives is promissory, but further modifications in processing must be necessary.
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