肯尼亚安扎盆地烃源岩的FTIR、XRF、XRD、GC-MS等多组分分析方法

Lorna Chemutai Chesir
{"title":"肯尼亚安扎盆地烃源岩的FTIR、XRF、XRD、GC-MS等多组分分析方法","authors":"Lorna Chemutai Chesir","doi":"10.13171/mjc023040171687chesir","DOIUrl":null,"url":null,"abstract":"Potential source rocks from three wells (Chalbi-3, Sirius-1, and Ndovu-1) in the Anza Basin of northeastern Kenya were analyzed using elemental carbon-hydrogen-nitrogen analysis, and mineralogical characterization by X-ray diffraction (XRD), X-ray fluorescence (XRF), Fourier transform infrared spectroscopy (FTIR), and scanning electron microscopy (SEM-EDX).). A Gas Chromatography-Mass Spectrometry (GC-MS) analysis of the saturated aliphatic biomarkers was carried out to illuminate the organic matter source. The analytical results revealed that the source rocks have moderate to high total organic carbon (%TOC) content, suggesting conditions in the Basin favor organic production and preservation. The Hydrogen Indices (HI: 0.19–0.60 atomic ratios) typify a predominance of mixed type II/III (oil/gas-prone) with more type III (gas-prone) and less II (oil-prone) kerogens. The FTIR, XRF, and XRD results reveal that the studied source rock samples comprised mainly of quartz, followed by silicate-clay minerals and calcite minerals. The solvent-extractable organic matter investigation revealed biomarker distributions of n-alkanes and isoprenoids (pristane/ phytane ratios), suggesting that source rocks were derived from algae and bacteria deposited weakly anoxic and low toxic environmental conditions, with minimal contribution from terrestrial organic matter sources. Consequently, all three wells have hydrocarbon generation potential, particularly Ndovu-1, which displays good organic matter content to produce oil and gas. The hydrocarbon potential is excellent and capable of making expulsions of oil and/or gas from the wells at sufficient depths.","PeriodicalId":18513,"journal":{"name":"Mediterranean Journal of Chemistry","volume":"33 2","pages":""},"PeriodicalIF":0.0000,"publicationDate":"2023-04-17","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Multi-analytical Approach (FTIR, XRF, XRD, GC-MS) Characterization of Source Rocks from the Anza Basin, Kenya\",\"authors\":\"Lorna Chemutai Chesir\",\"doi\":\"10.13171/mjc023040171687chesir\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"Potential source rocks from three wells (Chalbi-3, Sirius-1, and Ndovu-1) in the Anza Basin of northeastern Kenya were analyzed using elemental carbon-hydrogen-nitrogen analysis, and mineralogical characterization by X-ray diffraction (XRD), X-ray fluorescence (XRF), Fourier transform infrared spectroscopy (FTIR), and scanning electron microscopy (SEM-EDX).). A Gas Chromatography-Mass Spectrometry (GC-MS) analysis of the saturated aliphatic biomarkers was carried out to illuminate the organic matter source. The analytical results revealed that the source rocks have moderate to high total organic carbon (%TOC) content, suggesting conditions in the Basin favor organic production and preservation. The Hydrogen Indices (HI: 0.19–0.60 atomic ratios) typify a predominance of mixed type II/III (oil/gas-prone) with more type III (gas-prone) and less II (oil-prone) kerogens. The FTIR, XRF, and XRD results reveal that the studied source rock samples comprised mainly of quartz, followed by silicate-clay minerals and calcite minerals. The solvent-extractable organic matter investigation revealed biomarker distributions of n-alkanes and isoprenoids (pristane/ phytane ratios), suggesting that source rocks were derived from algae and bacteria deposited weakly anoxic and low toxic environmental conditions, with minimal contribution from terrestrial organic matter sources. Consequently, all three wells have hydrocarbon generation potential, particularly Ndovu-1, which displays good organic matter content to produce oil and gas. The hydrocarbon potential is excellent and capable of making expulsions of oil and/or gas from the wells at sufficient depths.\",\"PeriodicalId\":18513,\"journal\":{\"name\":\"Mediterranean Journal of Chemistry\",\"volume\":\"33 2\",\"pages\":\"\"},\"PeriodicalIF\":0.0000,\"publicationDate\":\"2023-04-17\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Mediterranean Journal of Chemistry\",\"FirstCategoryId\":\"1085\",\"ListUrlMain\":\"https://doi.org/10.13171/mjc023040171687chesir\",\"RegionNum\":0,\"RegionCategory\":null,\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"\",\"JCRName\":\"\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Mediterranean Journal of Chemistry","FirstCategoryId":"1085","ListUrlMain":"https://doi.org/10.13171/mjc023040171687chesir","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"","JCRName":"","Score":null,"Total":0}
引用次数: 0

摘要

采用元素碳-氢-氮分析方法对肯尼亚东北部Anza盆地3口井(Chalbi-3、Sirius-1和ndou -1)的潜在烃源岩进行了分析,并通过x射线衍射(XRD)、x射线荧光(XRF)、傅里叶变换红外光谱(FTIR)和扫描电镜(SEM-EDX)进行了矿物学表征。对饱和脂肪族生物标志物进行气相色谱-质谱(GC-MS)分析,阐明有机质来源。分析结果表明,烃源岩具有中~高的总有机碳(%TOC)含量,表明盆地条件有利于有机质的生成和保存。氢指数(HI: 0.19 ~ 0.60)表明,ⅱ型/ⅲ型(油气倾向)混合干酪根占优势,ⅲ型(气倾向)较多,ⅱ型(油倾向)较少。FTIR、XRF和XRD分析结果表明,烃源岩样品以石英矿物为主,其次为硅酸盐粘土矿物和方解石矿物。溶剂萃取有机质研究显示,正构烷烃和类异戊二烯类生物标志物(原生烷/植烷比值)的分布特征表明,烃源岩主要来源于弱缺氧低毒环境条件下的藻类和细菌沉积,陆源有机质贡献最小。因此,3口井均具有生烃潜力,特别是ndou -1井,有机质含量较高,具有良好的产气条件。油气潜力非常好,能够在足够深度的井中开采石油和/或天然气。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
查看原文
分享 分享
微信好友 朋友圈 QQ好友 复制链接
本刊更多论文
Multi-analytical Approach (FTIR, XRF, XRD, GC-MS) Characterization of Source Rocks from the Anza Basin, Kenya
Potential source rocks from three wells (Chalbi-3, Sirius-1, and Ndovu-1) in the Anza Basin of northeastern Kenya were analyzed using elemental carbon-hydrogen-nitrogen analysis, and mineralogical characterization by X-ray diffraction (XRD), X-ray fluorescence (XRF), Fourier transform infrared spectroscopy (FTIR), and scanning electron microscopy (SEM-EDX).). A Gas Chromatography-Mass Spectrometry (GC-MS) analysis of the saturated aliphatic biomarkers was carried out to illuminate the organic matter source. The analytical results revealed that the source rocks have moderate to high total organic carbon (%TOC) content, suggesting conditions in the Basin favor organic production and preservation. The Hydrogen Indices (HI: 0.19–0.60 atomic ratios) typify a predominance of mixed type II/III (oil/gas-prone) with more type III (gas-prone) and less II (oil-prone) kerogens. The FTIR, XRF, and XRD results reveal that the studied source rock samples comprised mainly of quartz, followed by silicate-clay minerals and calcite minerals. The solvent-extractable organic matter investigation revealed biomarker distributions of n-alkanes and isoprenoids (pristane/ phytane ratios), suggesting that source rocks were derived from algae and bacteria deposited weakly anoxic and low toxic environmental conditions, with minimal contribution from terrestrial organic matter sources. Consequently, all three wells have hydrocarbon generation potential, particularly Ndovu-1, which displays good organic matter content to produce oil and gas. The hydrocarbon potential is excellent and capable of making expulsions of oil and/or gas from the wells at sufficient depths.
求助全文
通过发布文献求助,成功后即可免费获取论文全文。 去求助
来源期刊
自引率
0.00%
发文量
0
期刊最新文献
Solid-Phase Separation and Green Removal of Amprolium Hydrochloride Veterinary Drug from Aqueous Media Using Dolomiaea Costus Roots as New Biosorbent Synthesis and Crystal Structure of Novel [(u-OCH6) (u-Cl) bis-[(bipy) (Cl)Cu(II)]]Complex In search of cytotoxic abietyl amides Crystal Structure and DFT Computations of a Solid-State Solution of Mixed Mononuclear Cu(II)/Co(II) Complex Influence of the activation method on the activity of the nickel catalyst
×
引用
GB/T 7714-2015
复制
MLA
复制
APA
复制
导出至
BibTeX EndNote RefMan NoteFirst NoteExpress
×
×
提示
您的信息不完整,为了账户安全,请先补充。
现在去补充
×
提示
您因"违规操作"
具体请查看互助需知
我知道了
×
提示
现在去查看 取消
×
提示
确定
0
微信
客服QQ
Book学术公众号 扫码关注我们
反馈
×
意见反馈
请填写您的意见或建议
请填写您的手机或邮箱
已复制链接
已复制链接
快去分享给好友吧!
我知道了
×
扫码分享
扫码分享
Book学术官方微信
Book学术文献互助
Book学术文献互助群
群 号:481959085
Book学术
文献互助 智能选刊 最新文献 互助须知 联系我们:info@booksci.cn
Book学术提供免费学术资源搜索服务,方便国内外学者检索中英文文献。致力于提供最便捷和优质的服务体验。
Copyright © 2023 Book学术 All rights reserved.
ghs 京公网安备 11010802042870号 京ICP备2023020795号-1