聚磷腈的数学建模

A. Abid, Shafiq Hussain, A. Qureshi, Muhammad Jamil, H. Rehman, A. Rauf
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引用次数: 0

摘要

本文合成了聚磷腈,并观察了其自组装行为。对不同聚合时间和温度条件下的聚合行为进行了实验研究。通过对实验数据的图形和统计分析,发现聚合现象受合成时间的控制,即Mw = Mo eksts,其中Mw为ts时刻聚合物的分子量,M0(=203.24)为模型中的指前因子,ks为(=10686)为聚合物的合成速率常数。
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Mathematical Modeling of Polyphosphazenes
Abstract Polyphosphazenes was synthesized and their self assembly behavior was observed as reported in our previous work [1–5]. A number of experiments were carried out to study the polymerization behavior at various conditions of the polymerization time and temperature. The experimental data were analyzed by graphical and statistical methods and it was found that the polymerization phenomena was controlled by the synthesis time, i.e. Mw = Mo eksts, where Mw is molecular weight of the polymer at time ts, M0(=203.24) is pre-exponential factor in the model and ks is (=10686) is synthesis rate constant for the polymer.
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