HMX在CO2激光波长下的振动谱:漂移和LPAS的联合研究

A. Puiu, G. Giubileo, S. Cesaro
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引用次数: 3

摘要

研究了固体标准HMX(八氢-1,3,5,7-四氮-1,3,5,7-四氮辛)的振动谱。采用了两种不同的光谱技术,其灵敏度和分辨率不同。利用漫反射红外傅里叶变换(DRIFT)技术,在室温下对化合物在8000 ~ 400cm−1光谱范围内的吸收带进行了初步研究。采用10 W稳定连续波CO2激光光源,采用激光光声光谱(LPAS)方法获得了HMX在9.2 ~ 10.8 μm光谱范围内的高分辨率谱线。通过比较两种技术在普通频率范围内收集的数据,观察到非常好的一致性。
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Vibrational Spectrum of HMX at CO2 Laser Wavelengths: A Combined DRIFT and LPAS Study
The vibrational spectrum of solid standard HMX (octahydro-1,3,5,7-tetranitro-1,3,5,7-tetrazocine) was investigated. Two spectroscopic techniques were adopted for their different sensitivity and resolution. A preliminary survey of the absorption bands of the compound was performed in the 8000–400 cm−1 spectral range by employing the diffuse reflectance infrared Fourier transform (DRIFT) technique at room temperature. The high-resolution line spectrum of HMX was obtained in the 9.2–10.8 μm spectral range by laser photoacoustic spectroscopy (LPAS) method, using a line tuneable 10 W stabilised cw CO2 laser light source. By comparing the data collected with the two techniques in the common frequency range, a very good agreement was observed.
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