Г.А. Мельников, Н.М. Игнатенко, К. Н. Болдырев, О.А. Манжос, А.С. Громков
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Характерные особенности низкочастотной области инфракрасных спектров и кластерная модель строения жидкостей
The results of experimental and theoretical studies of the low-frequency region of infrared spectra and Raman scattering spectra in liquid cyclic hydrocarbons (arenes) and their halogen-substituted ones are analyzed. The results of experimental studies of 13 liquids in the range 20–700 cm–1 using a high-resolution all-wavelength vacuum Fourier spectrometer (Bruker IFS 125 HR) are presented. It is shown that the appearance of spectral bands in the low-frequency region (the region of the “boson” peak) of the infrared spectra of liquids is due to the formation and decay of cluster formations in the structure of the liquid.
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