利用1.5 kWth太阳能/自热混合反应堆对含碳原料进行蒸汽气化

A. Muroyama, Iacopo Guscetti, Garrett L. Schieber, S. Haussener, P. Loutzenhiser
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引用次数: 1

摘要

提出了一种太阳能反应器与自热气化过程相结合的连续蒸汽气化方法,并进行了试验。在太阳能反应堆内自动热气化碳质原料的能力使合成气的全天候生产不受太阳瞬变的影响。通过平衡组分探讨合成气组分和产量的相关变化。部分原料燃烧导致合成气质量下降,尽管H2和CO仍然是主要的化学成分。采用蒙特卡罗射线追踪模型研究了不同原型反应堆构型对热流密度分布的影响。在高通量太阳模拟器上制作了原型反应器并进行了测试,分析了不同进口条件下反应器的时均响应。产物气体组成与使用平衡计算预测的相似。冷气比大于1表示原料的能量升级和模拟太阳能在产物气体化学键内的储存。提出了一种太阳能反应器与自热气化过程相结合的连续蒸汽气化方法,并进行了试验。在太阳能反应堆内自动热气化碳质原料的能力使合成气的全天候生产不受太阳瞬变的影响。通过平衡组分探讨合成气组分和产量的相关变化。部分原料燃烧导致合成气质量下降,尽管H2和CO仍然是主要的化学成分。采用蒙特卡罗射线追踪模型研究了不同原型反应堆构型对热流密度分布的影响。在高通量太阳模拟器上制作了原型反应器并进行了测试,分析了不同进口条件下反应器的时均响应。产物气体组成与使用平衡计算预测的相似。冷气比大于1表明原料有较大的升级。
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Steam gasification of carbonaceous feedstocks via a 1.5 kWth hybrid solar/autothermal reactor
A continuous method of steam gasification through hybridization of a solar reactor with an autothermal gasification process is proposed and tested. The ability to autothermally gasify a carbonaceous feedstock within a solar reactor enables round-the-clock production of syngas regardless of solar transients. Associated changes in syngas composition and production rate are explored through equilibrium compositions. Partial feedstock combustion results in an associated drop in syngas quality, although H2 and CO are still the primary chemical constituents. Monte Carlo ray-trace modeling was performed to examine the effect of different prototype reactor configurations on heat flux distributions. A prototype reactor was fabricated and tested in a high-flux solar simulator, and time-averaged responses to different inlet conditions were analyzed. Product gas compositions resembled those predicted using equilibrium calculations. Cold gas ratio values greater than unity indicated energetic upgrade of the feedstock and the storage of simulated solar energy within the chemical bonds of the product gases.A continuous method of steam gasification through hybridization of a solar reactor with an autothermal gasification process is proposed and tested. The ability to autothermally gasify a carbonaceous feedstock within a solar reactor enables round-the-clock production of syngas regardless of solar transients. Associated changes in syngas composition and production rate are explored through equilibrium compositions. Partial feedstock combustion results in an associated drop in syngas quality, although H2 and CO are still the primary chemical constituents. Monte Carlo ray-trace modeling was performed to examine the effect of different prototype reactor configurations on heat flux distributions. A prototype reactor was fabricated and tested in a high-flux solar simulator, and time-averaged responses to different inlet conditions were analyzed. Product gas compositions resembled those predicted using equilibrium calculations. Cold gas ratio values greater than unity indicated energetic upgrade of the feedstock ...
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