Waly Diallo, Boucar Diouf, Bougar Sarr, Mouhamadou Sembéne Boye, Pechev Stanislav Pavlov, F. Michaud
{"title":"半水合马来酸氢环己基铵盐的晶体结构","authors":"Waly Diallo, Boucar Diouf, Bougar Sarr, Mouhamadou Sembéne Boye, Pechev Stanislav Pavlov, F. Michaud","doi":"10.13171/mjc02301041662diallo","DOIUrl":null,"url":null,"abstract":"<p>The compound CyNH<sub>3</sub>[HOOC(CH)<sub>2</sub>COO]·H<sub>2</sub>O has been obtained using one pot-synthesis process by mixing, in methanol, HOOC(CH)<sub>2</sub>COOH, CyNH<sub>2</sub> and SnPh<sub>3</sub>Cl in a 1:1:1 molar ratio. X-ray diffraction analysis of the compound reveals that in the crystal structure, hydrogen maleate [HOOC(CH)<sub>2</sub>COO]<sup>-</sup> in cis configuration interacts with [CyNH<sub>3</sub>]<sup>+</sup> cations and water molecules to generate an R<sub>6</sub><sup>6</sup>(22) ring. The interconnections of the rings via simple (N–H··O and O–H··O) and bifurcated (N–H···(O, O)) hydrogen bonds give rise to a 2D supramolecular structure.</p>","PeriodicalId":18513,"journal":{"name":"Mediterranean Journal of Chemistry","volume":"28 1","pages":""},"PeriodicalIF":0.0000,"publicationDate":"2023-01-04","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"1","resultStr":"{\"title\":\"Crystal structure of cyclohexylammonium hydrogen maleate salt hemi-hydrated\",\"authors\":\"Waly Diallo, Boucar Diouf, Bougar Sarr, Mouhamadou Sembéne Boye, Pechev Stanislav Pavlov, F. Michaud\",\"doi\":\"10.13171/mjc02301041662diallo\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<p>The compound CyNH<sub>3</sub>[HOOC(CH)<sub>2</sub>COO]·H<sub>2</sub>O has been obtained using one pot-synthesis process by mixing, in methanol, HOOC(CH)<sub>2</sub>COOH, CyNH<sub>2</sub> and SnPh<sub>3</sub>Cl in a 1:1:1 molar ratio. X-ray diffraction analysis of the compound reveals that in the crystal structure, hydrogen maleate [HOOC(CH)<sub>2</sub>COO]<sup>-</sup> in cis configuration interacts with [CyNH<sub>3</sub>]<sup>+</sup> cations and water molecules to generate an R<sub>6</sub><sup>6</sup>(22) ring. The interconnections of the rings via simple (N–H··O and O–H··O) and bifurcated (N–H···(O, O)) hydrogen bonds give rise to a 2D supramolecular structure.</p>\",\"PeriodicalId\":18513,\"journal\":{\"name\":\"Mediterranean Journal of Chemistry\",\"volume\":\"28 1\",\"pages\":\"\"},\"PeriodicalIF\":0.0000,\"publicationDate\":\"2023-01-04\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"1\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Mediterranean Journal of Chemistry\",\"FirstCategoryId\":\"1085\",\"ListUrlMain\":\"https://doi.org/10.13171/mjc02301041662diallo\",\"RegionNum\":0,\"RegionCategory\":null,\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"\",\"JCRName\":\"\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Mediterranean Journal of Chemistry","FirstCategoryId":"1085","ListUrlMain":"https://doi.org/10.13171/mjc02301041662diallo","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"","JCRName":"","Score":null,"Total":0}
Crystal structure of cyclohexylammonium hydrogen maleate salt hemi-hydrated
The compound CyNH3[HOOC(CH)2COO]·H2O has been obtained using one pot-synthesis process by mixing, in methanol, HOOC(CH)2COOH, CyNH2 and SnPh3Cl in a 1:1:1 molar ratio. X-ray diffraction analysis of the compound reveals that in the crystal structure, hydrogen maleate [HOOC(CH)2COO]- in cis configuration interacts with [CyNH3]+ cations and water molecules to generate an R66(22) ring. The interconnections of the rings via simple (N–H··O and O–H··O) and bifurcated (N–H···(O, O)) hydrogen bonds give rise to a 2D supramolecular structure.
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