{"title":"纳米相ZnO和ZnO- al2o3纳米复合材料交流响应的阻抗谱分析","authors":"Joshy Jose , M.Abdul Khadar","doi":"10.1016/S0965-9773(99)00399-2","DOIUrl":null,"url":null,"abstract":"<div><p><span>Nanoparticles of ZnO and Al</span><sub>2</sub>O<sub>3</sub> were prepared by chemical arrested precipitation. The average particle size was determined from x-ray line broadening and TEM. The ac electrical response of the consolidated nanoparticles of ZnO and ZnO-Al<sub>2</sub>O<sub>3</sub><span> nanocomposites was studied using impedance spectroscopic technique. The equivalent circuit parameters were determined by computer simulation. The grain and grain boundary contributions to the conductivity were determined and the difference in the conductivity was attributed to the grain boundary properties of nanomaterials. The variation in conductivity of nanocomposites with weight percentage of Al</span><sub>2</sub>O<sub>3</sub><span> was attributed to the change in interfacial defect structure<span>, band structure modifications and compensation of oxygen vacancies.</span></span></p></div>","PeriodicalId":18878,"journal":{"name":"Nanostructured Materials","volume":"11 8","pages":"Pages 1091-1099"},"PeriodicalIF":0.0000,"publicationDate":"1999-11-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://sci-hub-pdf.com/10.1016/S0965-9773(99)00399-2","citationCount":"57","resultStr":"{\"title\":\"Impedance spectroscopic analysis of AC response of nanophase ZnO and ZnO-Al2O3 nanocomposites\",\"authors\":\"Joshy Jose , M.Abdul Khadar\",\"doi\":\"10.1016/S0965-9773(99)00399-2\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<div><p><span>Nanoparticles of ZnO and Al</span><sub>2</sub>O<sub>3</sub> were prepared by chemical arrested precipitation. The average particle size was determined from x-ray line broadening and TEM. The ac electrical response of the consolidated nanoparticles of ZnO and ZnO-Al<sub>2</sub>O<sub>3</sub><span> nanocomposites was studied using impedance spectroscopic technique. The equivalent circuit parameters were determined by computer simulation. The grain and grain boundary contributions to the conductivity were determined and the difference in the conductivity was attributed to the grain boundary properties of nanomaterials. The variation in conductivity of nanocomposites with weight percentage of Al</span><sub>2</sub>O<sub>3</sub><span> was attributed to the change in interfacial defect structure<span>, band structure modifications and compensation of oxygen vacancies.</span></span></p></div>\",\"PeriodicalId\":18878,\"journal\":{\"name\":\"Nanostructured Materials\",\"volume\":\"11 8\",\"pages\":\"Pages 1091-1099\"},\"PeriodicalIF\":0.0000,\"publicationDate\":\"1999-11-01\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"https://sci-hub-pdf.com/10.1016/S0965-9773(99)00399-2\",\"citationCount\":\"57\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Nanostructured Materials\",\"FirstCategoryId\":\"1085\",\"ListUrlMain\":\"https://www.sciencedirect.com/science/article/pii/S0965977399003992\",\"RegionNum\":0,\"RegionCategory\":null,\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"\",\"JCRName\":\"\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Nanostructured Materials","FirstCategoryId":"1085","ListUrlMain":"https://www.sciencedirect.com/science/article/pii/S0965977399003992","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"","JCRName":"","Score":null,"Total":0}
Impedance spectroscopic analysis of AC response of nanophase ZnO and ZnO-Al2O3 nanocomposites
Nanoparticles of ZnO and Al2O3 were prepared by chemical arrested precipitation. The average particle size was determined from x-ray line broadening and TEM. The ac electrical response of the consolidated nanoparticles of ZnO and ZnO-Al2O3 nanocomposites was studied using impedance spectroscopic technique. The equivalent circuit parameters were determined by computer simulation. The grain and grain boundary contributions to the conductivity were determined and the difference in the conductivity was attributed to the grain boundary properties of nanomaterials. The variation in conductivity of nanocomposites with weight percentage of Al2O3 was attributed to the change in interfacial defect structure, band structure modifications and compensation of oxygen vacancies.
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