The physical and mechanical properties of recycled aggregates strengthened by enzyme induced carbonate precipitation

Enzyme induced carbonate precipitation (EICP) which applied to improve the quality of recycled aggregates (RA) is a novel technology in the field of civil engineering. The urease was extracted from soybean, and the factors including soybean powder concentration, temperature and pH value on urease activity were investigated. Then the EICP reaction kinetics was carried out to obtain the most suitable reaction environment. A spraying method instead of soaking method for modifying RA was proposed, and the physical and mechanical properties of RA were evaluated by water absorption, hardness, apparent density and crushing index. The results show that the optimum pH value of soybean urease is 8.0, the concentration of soybean power is 40 g/L, and the urease activity increases with temperature in the range of 10–50 °C. Spraying method was better than soaking method in water absorption reduction rate of RA with different particle sizes. When the concentration of the chemical solution is 0.5 mol/L, the improvement in the water absorption characteristics of the RA is most significant. And the modified RA have also undergone substantial improvements in terms of hardness and apparent density. On the 7-day of modification, the crushing index of the RA reaches the peak. Through microscopic observation, the pore volume of the modified RA is significantly reduced, and the content of CaCO₃ is significantly increased, and the main crystalline form of CaCO₃ are calcite and vaterite.