非共轭氧化还原活性聚合物:电子转移机制、能量存储和化学多功能性。

IF 7.6 2区 工程技术 Q1 CHEMISTRY, APPLIED Annual review of chemical and biomolecular engineering Pub Date : 2023-06-08 DOI:10.1146/annurev-chembioeng-092220-111121
Ting Ma, Alexandra D Easley, Ratul Mitra Thakur, Khirabdhi T Mohanty, Chen Wang, Jodie L Lutkenhaus
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引用次数: 0

摘要

对于以技术为基础的现代社会来说,以安全、环保的方式储存电能的重要性与日俱增。由于预计未来含有战略金属的电池将面临压力,人们对无金属电极材料的兴趣与日俱增。在候选材料中,非共轭氧化还原活性聚合物(NC-RAPs)在成本效益、良好的加工性、独特的电化学性质以及针对不同电池化学性质的精确调节等方面具有优势。在此,我们回顾了有关氧化还原动力学机制、分子设计、合成以及 NC-RAPs 在电化学储能和转换中的应用的最新研究进展。我们比较了不同的氧化还原化学物质,包括聚醌类、聚酰亚胺类、聚酮类、含硫聚合物、含自由基聚合物、聚苯胺类、聚吩嗪类、聚吩噻嗪类、聚吩噁嗪类和聚维酮类。最后,我们介绍了考虑到电解质优化和电池配置的电池设计原则。最后,我们指出了未来有望设计出 NC-RAPs 的基础和应用领域。
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Nonconjugated Redox-Active Polymers: Electron Transfer Mechanisms, Energy Storage, and Chemical Versatility.

The storage of electric energy in a safe and environmentally friendly way is of ever-growing importance for a modern, technology-based society. With future pressures predicted for batteries that contain strategic metals, there is increasing interest in metal-free electrode materials. Among candidate materials, nonconjugated redox-active polymers (NC-RAPs) have advantages in terms of cost-effectiveness, good processability, unique electrochemical properties, and precise tuning for different battery chemistries. Here, we review the current state of the art regarding the mechanisms of redox kinetics, molecular design, synthesis, and application of NC-RAPs in electrochemical energy storage and conversion. Different redox chemistries are compared, including polyquinones, polyimides, polyketones, sulfur-containing polymers, radical-containing polymers, polyphenylamines, polyphenazines, polyphenothiazines, polyphenoxazines, and polyviologens. We close with cell design principles considering electrolyte optimization and cell configuration. Finally, we point to fundamental and applied areas of future promise for designer NC-RAPs.

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来源期刊
Annual review of chemical and biomolecular engineering
Annual review of chemical and biomolecular engineering CHEMISTRY, APPLIED-ENGINEERING, CHEMICAL
CiteScore
16.00
自引率
0.00%
发文量
25
期刊介绍: The Annual Review of Chemical and Biomolecular Engineering aims to provide a perspective on the broad field of chemical (and related) engineering. The journal draws from disciplines as diverse as biology, physics, and engineering, with development of chemical products and processes as the unifying theme.
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