Surface Modulation of SiGe by Hydrogen Plasma Process with Site Exchange Mechanism between Si and Ge

Y. Ishii, R. Sugano, Yao-Jen Lee, Wen-Fa Wu, K. Maeda, M. Miura
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Abstract

We present hydrogen plasma treatment at low temperature that modulates SiGe surface. In this study, we investigated the mechanism of SiGe surface modification after hydrogen plasma exposure, which produces a Si-rich surface. We reveal the mechanism of the surface modulation, which is induced by Si surface segregation (i.e., ion-energy induced site exchange between Si and Ge across different layers). We also propose an ion-energy localization model that drives the Si segregation. Ab-initio calculation also proves how energetically favorable the site exchange is.
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氢等离子体工艺对SiGe的表面调制及其在Si和Ge之间的位置交换机制
我们提出了低温氢等离子体处理,调节SiGe表面。在本研究中,我们研究了氢等离子体暴露后SiGe表面改性的机理,从而产生富硅表面。我们揭示了表面调制的机制,这是由Si表面偏析(即,离子能量诱导的Si和Ge在不同层之间的位置交换)引起的。我们还提出了一个驱动硅偏析的离子能量局域化模型。从头算也证明了位置交换在能量上是多么有利。
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