Application of Membrane Processes for Nitrate (NO3-) Removal

Ö. Arar, Cesur Mehenktaş
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Abstract

The primary sources of nitrate contamination in groundwater resources are excessive fertilizer use and unregulated land discharges of treated wastewater. Because of its harmful nature to human health and its contribution to eutrophication, the removal of nitrate from water has been of great interest in the last decades. Various techniques such as adsorption, ion exchange, catalytic and biological denitrification, and membrane processes have been applied for NO3- removal. In this review paper, the removal of NO3- by membrane processes, including electrodialysis (ED), electrodeionization (EDI), reverse osmosis (RO), and ultrafiltration, have been reviewed. The pressure-driven membrane and electro-membrane processes applications to NO3- removal have been reviewed. The effect of process parameters, interferences, and limitations of membrane processes have been summed up. Membrane processes could be a promising alternative for NO3- removal. After suitable membrane preparation/modification, the nitrate removal rate could reach >99%.
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膜法去除硝酸盐(NO3-)的应用
地下水中硝酸盐污染的主要来源是过度使用肥料和未经管制的土地排放处理过的废水。由于硝酸盐对人体健康的危害及其对富营养化的贡献,过去几十年来,从水中去除硝酸盐一直是人们非常感兴趣的问题。吸附法、离子交换法、催化反硝化法、生物反硝化法、膜法等技术已被广泛应用于NO3-的去除。本文综述了电渗析(ED)、电去离子(EDI)、反渗透(RO)和超滤等膜法去除NO3-的研究进展。综述了压力驱动膜法和电膜法在NO3脱除中的应用。总结了工艺参数的影响、干扰和膜法的局限性。膜法是一种很有前途的去除NO3-的方法。经过适当的膜制备/改性,硝酸盐去除率可达>99%。
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