A TECHNICAL STUDY OF RED PAINTS IN THE RETOUCHING LAYER OF SOME WET-COLLODION GLASS PLATE NEGATIVES OF GOLESTAN PALACE PHOTO ARCHIVE

S. Noohi, Manijeh Hadian-Dehkordi
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Abstract

This study presents a part of a research project on retouching wet Collodion and dry gelatine glass plate negatives from Golestan Palace photo archive in Tehran, Iran, dating from the mid-19th century. The collection belongs to Qajar era. This is a case study on the use of red paint in retouching wet collodion glass plate negatives and aims to help the understanding of retouching material and their application. Red paints in four retouched negatives, and also their binder, identified in this study by means of, micro Fourier transform infrared (µ-FTIR), scanning electron microscopy-energy dispersive spectroscopy (SEM-EDS) and stereo microscopy technique. Elemental analysis performed with (SEM-EDS) revealed the presence of Lead (Pb), and Iron (Fe) elements in the paint. Thus, red Iron & red Lead pigments were identified as the red paints. The results confirmed by micro Fourier transform infrared (µ-FTIR), and a natural resin (probably gum Arabic) is identified as the binder of all paints as well. Red Lead, is realized as a paint to cover the boundaries, create more brightness, and as a binder to adhere masking papers, to the intended areas. Red Iron, is also found as a paint to correct emulsion defects and, make a perfectly clear and clean sky or background. Apparently, all these choices have been made consciously. It is believed that this study will contribute much to better understanding of retouching materials and the need to preserve them.
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古列斯坦宫照片资料馆部分湿胶玻璃底片修片层用红漆的技术研究
本研究展示了一个研究项目的一部分,该项目是对19世纪中期伊朗德黑兰戈列斯坦宫照片档案中的湿胶和干明胶玻璃板底片进行润饰的。这些藏品属于卡扎尔时代。这是一个使用红漆修饰湿胶玻璃板负片的案例研究,旨在帮助理解修饰材料及其应用。在本研究中,通过微傅里叶变换红外(µ-FTIR)、扫描电子显微镜-能量色散光谱(SEM-EDS)和立体显微镜技术,鉴定了四幅修饰过的底片上的红色颜料及其粘合剂。元素分析(SEM-EDS)显示,油漆中存在铅(Pb)和铁(Fe)元素。因此,红铁和红铅颜料被确定为红色颜料。微傅里叶变换红外(µ-FTIR)证实了这一结果,并确定了一种天然树脂(可能是阿拉伯树胶)是所有涂料的粘合剂。红铅,实现作为涂料覆盖边界,创造更多的亮度,并作为粘合剂,以坚持掩蔽纸,到预期的区域。红铁,也被发现作为一种油漆,以纠正乳剂缺陷,使一个完美的清晰和干净的天空或背景。显然,所有这些选择都是有意识的。相信本研究将有助于更好地理解修图材料及其保存的必要性。
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