Are PBDEs In Marine Sediments From The Coast Of Baja California Mexico Increasing In Time? A Problem Revisited

J. V. Macías-Zamora, N. Ramírez-Álvarez, F. A. Hernández-Guzmán, Cristina Quezada-Hernández
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Abstract

- We report here on the finding for PBDEs in coastal marine sediments in the south end of the Southern California Bight. We propose that there are two main contributors to the distribution of these chemicals in this part of the world for the surface distribution and composition of the PBDEs found. On the one hand, the presence of potential local sources such as wastewater treatment plants and on the other, the energy in the area provided mainly from the currents, the winds and waves for each area (North, Central, and South) and a third component due to the local topography. The range of concentrations for the sum of 14 PBDEs was; from undetected to a maximum of 9.74 ng/g dry weight. Generally, the largest concentrations coincided with samples collected in the deeper sites and located to the north. As previously found, the BDE-209 is predominant congener which indicates the trend given the discontinued commercial use of Penta-BDE and the Octa-BDE mixtures while maintaining still in use the Deca mixture. We also found an apparent increase in concentrations for the sum of these 14 PBDEs analysed as compared to that reported by us in 2013.
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墨西哥下加利福尼亚海岸海洋沉积物中的多溴二苯醚是否随时间增加?重新审视的问题
-我们在这里报告在南加州湾南端沿海海洋沉积物中发现的多溴二苯醚。对于所发现的多溴二苯醚的表面分布和组成,我们认为有两个主要因素导致了这些化学品在世界这一地区的分布。一方面,存在潜在的当地资源,如废水处理厂,另一方面,该地区的能源主要来自每个地区(北部、中部和南部)的洋流、风和海浪,第三部分是由于当地的地形。14种多溴二苯醚之和的浓度范围为;从未检测到最高9.74纳克/克干重。一般来说,最大的浓度与在较深的地点收集的样品一致,并且位于北部。如前所述,BDE-209是主要的同系物,这表明了五溴二苯醚和八溴二苯醚混合物已停止商业使用,而十溴二苯醚混合物仍在使用的趋势。我们还发现,与我们2013年报告的浓度相比,这14种多溴二苯醚的浓度总和明显增加。
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