Removal Of Pesticides From Waters With Zeolites And Zeolite-Carbon Composites

M. Andrunik, M. Skalny, T. Bajda
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Abstract

Extended Abstract The presence of pesticides in water, soil, and air has been recognized as a major environmental problem. Only a small part of the applied amount of a pesticide is active. Most of them are distributed in the environment. Inactive pesticides remain attached to the soil or dust particles, are leached out, migrate into the groundwater, and are distributed by surface runoff. A certain quantity reaches the air and can diffuse over long distances [1]. There are few technologies for the removal of pesticides. Physical remediation, based on the process of adsorption, is one of the most widely applied methods for water purification due to its efficiency, capacity, and applicability on a large scale. In present work, we aimed to prepare and investigate unmodified and surfactant-modified fly ash-based zeolites and zeolite-carbon composites as adsorbents of four pesticides: 2-(2,4-dichlorophenoxy)acetic acid (2,4-D) and 2-(4-chloro-2-methylphenoxy)acetic acid (MCPA), 6-chloro-2-N,4-N-diethyl-1,3,5-triazine-2,4-diamine (simazine) and methyl N-(1H-benzimidazol-2-yl)carbamate (carbendazim). Adsorbents were modified
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沸石及沸石-碳复合材料去除水中农药的研究
水、土壤和空气中农药的存在已被认为是一个重大的环境问题。施用的农药中只有一小部分是有效的。它们大多分布在环境中。不活跃的农药仍然附着在土壤或灰尘颗粒上,被浸出,迁移到地下水中,并通过地表径流分布。有一定量到达空气中并能长距离扩散[1]。去除农药的技术很少。基于吸附过程的物理修复因其效率高、容量大、适用范围广,是目前应用最广泛的水净化方法之一。在本工作中,我们旨在制备和研究未经改性和表面活性剂改性的粉煤灰基沸石和沸石-碳复合材料作为4种农药的吸附剂:2-(2,4-二氯-2-甲基苯氧基)乙酸(2,4-d)和2-(4-氯-2-甲基苯氧基)乙酸(MCPA), 6-氯-2-N,4-N-二乙基-1,3,5-三嗪-2,4-二胺(simmazine)和甲基N-(1h -苯并咪唑-2-基)氨基甲酸酯(多菌灵)。对吸附剂进行了改性
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