A quick method to determine the impurity content in gold ornaments by LIBS technique

A. Haider, S. Sengupta, K. M. Abedin
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引用次数: 2

Abstract

Laser induced breakdown spectroscopy (LIBS) and low energy dispersive X-ray fluorescence (ED-XRF) spectrometer, were used to determine the line intensity and concentration ratios of the major impurities (Cu and Ag) with respect to Au in gold ornaments with different caratage. Calibration curves were drawn with the data sets, obtained from LIBS and XRF, and from these calibration curves the unknown caratage of gold ornaments were obtained by using the line intensity of elements determined by LIBS. We have demonstrated the accuracy of this method by comparing the result with the carat value obtained by typical XRF method. This is yet another novel application of LIBS as a versatile analytic technique.
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液相色谱法快速测定金饰中杂质含量
采用激光诱导击穿光谱(LIBS)和低能量色散x射线荧光(ED-XRF)光谱仪测定了不同纯度金饰中主要杂质(Cu和Ag)相对于Au的谱线强度和浓度比。利用LIBS和XRF数据集绘制校准曲线,利用LIBS测定元素的线强度,从校准曲线中得到金饰的未知重量。通过与典型XRF法测定克拉值的比较,证明了该方法的准确性。这是LIBS作为一种通用分析技术的另一种新颖应用。
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