FTIR Reflectivity spectra of Thermoelectric K2Sb8Se13 crystals

E. Hatzikraniotis, T. Hassapis, T. Kyratsi, K. Paraskevopoulos, M. Kanatzidis
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Abstract

Investigations of ternary and quaternary compounds, Bi and Sb chalcogenides, have shown that several multinary compounds containing alkali metals present promising thermoelectric properties. In this work, the FTIR reflectivity spectra of K2Sb8Se13 crystals are reported and analyzed for the first time. Optical investigations are conducted with or without polarization, in two directions, parallel and perpendicular to the needles. The observed distinct optical anisotropy investigated by means of polarization dependent reflectivity measurements is discussed with respect to the strong structural anisotropy
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热电K2Sb8Se13晶体的FTIR反射率光谱
对三元和四元化合物铋和锑硫族化合物的研究表明,几种含碱金属的多元化合物具有良好的热电性能。本文首次报道并分析了K2Sb8Se13晶体的FTIR反射率光谱。光学调查进行有或没有偏振,在两个方向,平行和垂直于针。讨论了利用偏振相关反射率测量所观察到的明显的光学各向异性与强结构各向异性的关系
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