Growth Kinetics and Integration of Inorganic Nanowires for Flexible Electronics

D. Shakthivel, Adamos Christou, A. Dahiya, R. Dahiya
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Abstract

Inorganic NWs in the sub-100 nm diameter range have shown great potential for flexible electronics. Research in this area is governed by the three distinct domains, (1) growth strategy of NWs, (2) NWs printing, (3) development of flexible devices. These three domains are interdependent and the current works aims to show the connectivity via a generalized vapor-liquid-solid (VLS) based high temperature bottom-up growth process, which serves a key role to produce high quality NWs of length ~10-50 µm. These NWs are printed over a flexible substrates using contact or direct roll transfer printing techniques, eventually leading to flexible devices. The key requirement from the growth process is to obtain long NWs needed for effective printing. Here we discuss the growth of NWs suitable for printing via atomistic kinetic model. This is followed by contact printing of vertical grown NWs over flexible substrates to develop an array of flexible ZnO NWs FETs with uniform response.
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柔性电子用无机纳米线的生长动力学与集成
直径在100纳米以下的无机纳米在柔性电子领域显示出巨大的潜力。该领域的研究由三个不同的领域主导,(1)新纳米粒子的增长策略,(2)新纳米粒子的打印,(3)柔性器件的开发。这三个领域是相互依存的,目前的工作旨在通过基于蒸汽-液体-固体(VLS)的高温自下而上生长过程来展示它们的连通性,这对于产生长度为10-50µm的高质量NWs起着关键作用。这些NWs使用接触或直接滚转印刷技术印刷在柔性基材上,最终导致柔性设备。生长过程的关键要求是获得有效打印所需的长NWs。本文通过原子动力学模型讨论了适合印刷的纳米粒子的生长。然后在柔性衬底上进行垂直生长的NWs接触印刷,以开发具有均匀响应的柔性ZnO NWs场效应管阵列。
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