Synthesis and characterization of the interaction of ZnO and CdTe photoluminescent quantum dots for photovoltaic applications

F. Orona-Magallanes, R. Guerrero-Gonzalez, A. Zazueta-Raynaud, A. Ayón, J. E. Pelayo, R. Ruelas, E. Saucedo-Flores
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Abstract

We discuss the synthesis of zinc oxide (ZnO) and cadmium telluride (CdTe) quantum dots (QDs), the characterization of their optical properties on their own as well as combined, and their influence on the power conversion efficiency of photovoltaic structures when the QD blends were dispersed in a polymeric solution and deployed on the window surface of polycrystalline Si solar cells as down-shifting photoluminescent (PL) coatings. Upon the incorporation of increasing amounts of ZnO QDs into a colloidal solution of CdTe, the characteristic CdTe PL peak location was monotonically red-shifted from 598 nm to 611 nm. A 1:3 volumetric combination CdTe:ZnO QDs exhibited a the power conversion efficiency increase from 14.71% for an uncoated solar cell to 15.02% with the QD layer, that is, an approximate improvement of approximately 2%.
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用于光伏应用的ZnO和CdTe光致发光量子点的合成和相互作用的表征
我们讨论了氧化锌(ZnO)和碲化镉(CdTe)量子点(QDs)的合成,它们各自和组合的光学性质的表征,以及当QD共混物分散在聚合物溶液中并作为下移光致发光(PL)涂层部署在多晶硅太阳能电池的窗口表面时,它们对光伏结构的功率转换效率的影响。在CdTe胶体溶液中加入越来越多的ZnO量子点后,CdTe的特征PL峰位置从598 nm单调红移到611 nm。在体积为1:3的CdTe:ZnO量子点组合中,太阳能电池的功率转换效率从未涂覆的14.71%提高到有量子点层的15.02%,大约提高了2%。
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