The Effect of Zeolite Catalysis Size on Biodiesel Characteristics of Bio-Oil from Tuna Waste

I. Rosyadi, H. Haryadi, Ni Ketut Caturwati, Syahrul Ivandy
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Abstract

Indonesia is a country with the third largest tuna production in the world. Fish oil as a fishery product processing waste is a potential material for making biodiesel because it has a high fat content. In this research, biodiesel was made from bio-oil from tuna waste through esterification and transesterification processes at 60°C, stirring speed 360 rpm with a reaction time of 2 hours. The purpose of this study was to determine the levels of Free Fatty Acid (FFA) contained in bio-oil from tuna waste and to determine the effect of the size of the natural zeolite catalyst in the transesterification process on the characteristics of the biodiesel produced. The variables used were the size of the zeolite catalyst 10 - 20, 30 - 40, 50 - 60, 70 - 80, 100 - 120 mesh. From the research results, it can be concluded that the smaller the zeolite catalyst size, the resulting biodiesel is closer to the biodiesel standard and the size of 100-120 mesh which is very close to the SNI 7182: 2015 biodiesel standard with a density value of 849.6 kg/m 3 , kinematic viscosity 3,413 cSt, moisture content. 0%, acid number 1.10 mg.KOH /gr, flash point 75 ° C, calorific value 8.240 Cal/gr.
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沸石催化粒径对金枪鱼废生物油生物柴油特性的影响
印度尼西亚是世界第三大金枪鱼生产国。鱼油作为一种水产品加工废弃物,脂肪含量高,是生产生物柴油的潜在原料。本研究以金枪鱼废弃物生物油为原料,在60℃、搅拌速度360 rpm、反应时间2小时的条件下,通过酯化和酯交换工艺制备生物柴油。本研究的目的是确定金枪鱼废料生物油中游离脂肪酸(FFA)的含量,并确定酯交换过程中天然沸石催化剂的大小对所制生物柴油特性的影响。使用的变量是沸石催化剂的尺寸10 - 20,30 - 40,50 - 60,70 - 80,100 - 120目。从研究结果可以看出,沸石催化剂粒径越小,所得生物柴油越接近生物柴油标准,粒径为100-120目,非常接近SNI 7182: 2015生物柴油标准,密度值为849.6 kg/m 3,运动粘度3413 cSt,含水率。0%,酸值1.10 mg。KOH /gr,闪点75℃,发热量8.240 Cal/gr。
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