Synthesis, characterization and electrical properties of glass-ceramic samples of MIxNa4−xCoFe(PO4)3 (MI - Li, K) composition

M. Bondarenko, N. Strutynska, I. Zatovsky, R. Kuzmin, N. Slobodyanik
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Abstract

The vitreous samples of MIxNa4-xCoFe(PO4)3 (x = 0, 0.2 and 1.0, MI - Li, K) composition were prepared by melt method. Formation of Nasicon-related crystalline samples was caused by the annealing at 600 °C. The cell parameters calculation showed that its evolution along two series agrees with the substitution of Na+ by smaller Li+ and bigger K+ cations. The electrical properties were investigated by the impedance method.
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MIxNa4−xCoFe(PO4)3 (MI - Li, K)成分玻璃陶瓷样品的合成、表征及电学性能
采用熔融法制备了MIxNa4-xCoFe(PO4)3 (x = 0,0.2和1.0,MI - Li, K)组成的玻璃样品。在600℃的退火条件下,形成了与nasicon相关的晶体样品。电池参数计算表明,其沿两个系列的演变符合Na+被较小的Li+和较大的K+阳离子取代。用阻抗法对其电性能进行了研究。
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