Device Modeling of Double Layered TiO2 Nanotube Array Based Resistive Vapor Sensor

A. Hazra
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Abstract

Single and double layered TiO2nanotube array were synthesized by anodic oxidation method. Anodization voltage was varied to develop double layered TiO2nanotube array. Developed materials were characterized structurally and morphologically by X-ray diffraction spectroscopy (XRD)and field emission scanning electron microscopy (FESEM)respectively. Sandwich structure devices with Au top electrode and Ti bottom electrode were fabricated by using both single and double layered TiO2nanotubes for vapor sensing application. A simplified device modeling was introduced to establish the sensing mechanism of both the TiO2nanotube arrays. Additional interlayer junctions in double layered TiO2nanotubes array, enhanced the vapor sensing performance significantly. Double layered TiO2nanotubes array was able to show 92.4% of response magnitude for ethanol concentration of 160 ppm at 300 K where 55.2% response was observed for mono-layered TiO2nanotube array.
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基于双层TiO2纳米管阵列的电阻式蒸汽传感器器件建模
采用阳极氧化法制备了单层和双层tio2纳米管阵列。改变阳极氧化电压,形成双层tio2纳米管阵列。利用x射线衍射光谱(XRD)和场发射扫描电镜(FESEM)对制备的材料进行了结构和形貌表征。采用单层和双层tio2纳米管分别制备了上电极为Au、下电极为Ti的夹层结构气敏器件。采用简化的器件建模方法建立了两种tio2纳米管阵列的传感机理。在双层tio2纳米管阵列中增加层间结,显著提高了其气敏性能。当乙醇浓度为160 ppm, 300k时,双层tio2纳米管阵列的响应幅度为92.4%,单层tio2纳米管阵列的响应幅度为55.2%。
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