Raman spectroscopy study of SiC thin films prepared by PECVD for solar cell working in hard environment

V. Sasinková, J. Huran, A. Kleinová, P. Boháček, J. Arbet, M. Sekáčová
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引用次数: 3

Abstract

Amorphous silicon carbide films were deposited by plasma enhanced chemical vapor deposition (PECVD) technology using SiH4, CH4, H2 and NH3 gas as precursors. The concentration of elements in the films was determined by RBS and ERD analytical method. Chemical compositions were analyzed by FT-IR spectroscopy. Raman spectroscopy study of the SiC films were performed by using a Raman microscope. Irradiation of samples with neutrons to fluencies A(7.9x1014 cm-2), B(5x1015 cm-2) and C(3.4x1016 cm-2) was performed at room temperature. Raman spectroscopy results of SiC films showed decreasing of Raman band feature intensity after neutron irradiation and slightly decreased with increased neutron fluencies. Raman spectra differences between types of films before and after neutron irradiation are discussed. The electrical properties of SiC films were determined by the I-V measurement at 295 K. The measured currents were greater (about two order) after irradiation than the current before irradiation for all samples and rose up with neutron fluencies.
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硬质环境下太阳能电池用PECVD制备SiC薄膜的拉曼光谱研究
以SiH4、CH4、H2和NH3气体为前驱体,采用等离子体增强化学气相沉积(PECVD)技术制备了非晶碳化硅薄膜。采用RBS和ERD分析方法测定了膜中元素的浓度。用傅里叶变换红外光谱分析其化学成分。利用拉曼显微镜对SiC薄膜进行了拉曼光谱研究。在室温下用中子照射样品到A(7.9x1014 cm-2), B(5x1015 cm-2)和C(3.4x1016 cm-2)。碳化硅薄膜的拉曼光谱结果表明,中子辐照后,薄膜的拉曼带特征强度减小,随中子通量的增加略有减小。讨论了中子辐照前后不同类型薄膜的拉曼光谱差异。在295 K下,通过I-V测量测定了SiC薄膜的电学性能。所有样品辐照后测得的电流都比辐照前大(约两个数量级),且随中子通量的增大而增大。
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