Efficiency enhancement of semitransparent organic solar cells by using printed dielectric mirrors (Presentation Recording)

Carina Bronnbauer, K. Forberich, Fei Guo, N. Gasparini, C. Brabec
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Abstract

Building integrated thin film solar cells are a strategy for future eco-friendly power generation. Such solar cells have to be semi-transparent, long-term stable and show the potential to be fabricated by a low-cost production process. Organic photovoltaics are a potential candidate because an absorber material with its main absorption in the infrared spectral region where the human eye is not sensitive can be chosen. We can increase the number of absorbed photons, at the same time, keep the transparency almost constant by using a dielectric, wavelength-selective mirror. The mirror reflects only in the absorption regime of the active layer material and shows high transparencies in the spectral region around 550 nm where the human eye is most sensitive. We doctor bladed a fully solution processed dielectric mirror at low temperatures below 80 °C. Both inks, which are printed alternatingly are based on nanoparticles and have a refractive index of 1.29 or 1.98, respectively, at 500 nm. The position and the intensity of the main reflection peak can be easily shifted and thus adjusted to the solar cell absorption spectrum. Eventually, the dielectric mirror was combined with different organic solar cells. For instance, the current increases by 20.6 % while the transparency decreases by 23.7 % for the low band gap absorber DPP and silver nanowires as top electrode. Moreover we proved via experiment and optical simulations, that a variation of the active layer thickness and the position of the main reflection peak affect the transparency and the increase in current.
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利用印刷介质镜提高半透明有机太阳能电池的效率(演讲记录)
集成薄膜太阳能电池是未来环保发电的战略。这种太阳能电池必须是半透明的,长期稳定的,并显示出通过低成本生产工艺制造的潜力。有机光伏是一个潜在的候选者,因为可以选择一种吸收材料,其主要吸收在人眼不敏感的红外光谱区域。我们可以增加吸收光子的数量,同时,通过使用介电波长选择性反射镜,保持透明度几乎恒定。反射镜仅在活性层材料的吸收区反射,并在人眼最敏感的550 nm左右的光谱区域显示高透明度。我们在低于80°C的低温下进行了全溶液处理的介电镜。这两种交替印刷的油墨都是基于纳米颗粒,在500纳米处的折射率分别为1.29或1.98。主反射峰的位置和强度可以很容易地移位,从而调整到太阳能电池的吸收光谱。最终,介质镜与不同的有机太阳能电池结合在一起。例如,低带隙吸收剂DPP和银纳米线作为顶电极时,电流增加了20.6%,而透明度下降了23.7%。此外,通过实验和光学模拟证明,有源层厚度和主反射峰位置的变化会影响透明度和电流的增加。
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