Optimisation of simulation of diffusional transport to microsphere electrode and its application to electrogenerated chemiluminescence

I. Svir, A. Oleinick, Richard G. Compton
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Abstract

We show the application of the three layer finite implicit (3LFI) method for finding a solution of the ECL diffusion microsphere problem during bipolar impulse non-stationary electrolysis. Two different transformed coordinates in the radial coordinate were employed, a conformal map and an exponentially expanding grid, with aim of optimising the modelling of the diffusion under non steady state conditions.
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微球电极扩散输运模拟优化及其在电致化学发光中的应用
我们展示了三层有限隐式(3LFI)方法在寻找双极脉冲非平稳电解过程中ECL扩散微球问题的解的应用。为了优化非稳态条件下的扩散模型,在径向坐标系中采用了两种不同的变换坐标:保角映射和指数扩展网格。
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