Comparison of Effects of Alkaline Activator Molarity and Cure Temperature for Geopolymer Synthesized from Alternative Laterite Sources

K. Oluborode, I. Olofintuyi, O. R. Olulope
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Abstract

Geological source material remains one of the options for developing countries to participate in deployment of geopolymer material technology for environmental friendly infrastructure development. Geological source materials for geopolymer are heterogeneous in nature. This study sort to investigate and provide information for aggregation of repository comparative information on geopolymer specimen properties of alternative source material and their response to effect of alkaline activator molarity and cure temperatures. Pulverized 750°c calcined laterite obtained from two alternate sources were activated with alkaline activator solution of NaOH of 8M, 10M, and 12M with NaSiO3 and sterile water of ratio 7:3:3 were properly mixed at activator to source material ratio of 0.45. 50×50×50 specimen cubes were cast for density, porosity and comprehensive strength test for specimen cure at 27°c (room temperature), and 50°c and 90°c in oven temperature respectively for 28 days and 72 hours. The study shows that in each geopolymer specimen source material, the density of the specimen decreases with increased cure temperature while specimen porosity increases with increased cure temperature. Increased activator molarity increases the density of the specimen while specimen porosity does not follow a definite trend with activator molarity. Ekiti parapo pavilion laterite based geopolymer specimen has minimum density, porosity and comprehensive strength of 2.15 g/cm³, 5.27% and 1.74 N/mm². Geopolymer specimen based on polytechnic gate source material have density, porosity and compressive strength minimum values of 1.86 g/cm³, 11.46% and 0.58 N/mm2.. Their corresponding maximum values are respectively 2.40 g/cm³, 19.24% and 14.92 N/mm2 for pavilion based geopolymer specimens, 2.33 g/cm³, 26.08% and 6.90 N/mm².
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碱性活化剂摩尔浓度和固化温度对不同红土源合成地聚合物影响的比较
地质源材料仍然是发展中国家参与为环境友好型基础设施发展部署地聚合物材料技术的选择之一。地聚合物的地质源物质在性质上是不均匀的。本研究旨在探讨不同源材料的地聚合物样品性质及其对碱性活化剂摩尔浓度和固化温度影响的响应,为聚合库比较资料提供信息。将750°c煅烧红土粉碎后,用8M、10M、12M的NaOH碱性活化剂溶液与NaSiO3和比例为7:3:3的无菌水混合,活化剂与源料比为0.45。50×50×50铸块进行密度、孔隙率和综合强度测试,试件在27℃(室温)、50℃和90℃的烘箱温度下分别固化28天和72小时。研究表明,在各地聚合物试样源材料中,试样密度随固化温度的升高而减小,孔隙率随固化温度的升高而增大。活化剂的摩尔浓度增加会增加试样的密度,而试样的孔隙率不随活化剂的摩尔浓度的增加而变化。Ekiti parapo pavilion红土基地聚合物试样的最小密度、孔隙率和综合强度分别为2.15 g/cm³、5.27%和1.74 N/mm²。基于工艺栅源材料的地聚合物试样密度、孔隙率和抗压强度最小值分别为1.86 g/cm³、11.46%和0.58 N/mm2。其最大值分别为2.40 g/cm³,19.24%和14.92 N/mm2, 2.33 g/cm³,26.08%和6.90 N/mm²。
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