Optimization by response surface methodology. Application to rare earth elements recovery

Y. T. Alaoui, N. S. A. Hassani, D. Khomsi
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Abstract

This work focuses on the leaching process of rare earth elements (REEs) from phosphor powder (PP) in order to reach optimal conditions of REEs recovery. Investigated PP was characterized in our previous work, after recovering from waste linear tube fluorescent lamps (FLs). Hydrochloric acid effect on leaching efficiency of REEs from PP is studied. Response surface methodology is used to determine the optimum leaching conditions. Obtained results show that, using 24.S% (v/v) HC1 at 90ºC, 140ml/gL/S ratio and 3h of leaching time, 99% of yttrium is leached out from the studied PP. Due to the highest content of major contaminant (calcium) present in obtained leach liquor, leachant agent (HC1) employed in this study may affect subsequent processes.
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响应面法优化。稀土元素回收的应用
研究了磷粉(PP)中稀土元素的浸出工艺,以获得稀土元素的最佳回收条件。在我们之前的工作中,从废弃的线形荧光灯(FLs)中回收所研究的PP进行了表征。研究了盐酸对PP中稀土元素浸出率的影响。采用响应面法确定最佳浸出条件。得到的结果表明,使用24。S% (v/v) HC1, 90℃,140ml/gL/S,浸出时间3h, 99%的钇从所研究的PP中浸出。由于所获得的浸出液中主要污染物(钙)含量最高,本研究中使用的浸出剂(HC1)可能会影响后续工艺。
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