Sol-gel process ZnO thin film as the electron transport layer in inverted polymer solar cell

Mei-Ying Chang, Chun-Chiao Lin, Chih-Kuo Huang
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引用次数: 1

Abstract

In this paper, we used sol-gel derived ZnO solution of different molar ratio of ethanolamine with low temperature process deposited on ITO substrate as the electron transport layer (ETL) in inverted polymer solar cells (IPSCs). We found through a detailed analysis of less ethanolamine and low-temperature process ZnO thin film, which gives both high transparency and comparative literature has a simple process and control the film surface morphology, and low-temperature process of flexible, this increases the short-circuit density from 7.01 to 8.20mA/cm2 at an annealing temperature of 150°C for 10min. The flexible IPSCs exhibit a PCE of 2.48 to 3.17% for poly(3-hexylthiophene):[6,6]-phenyl C61 butyric acid methyl ester (P3HT:PC61BM) blend film as the active layer under simulated AM1.5G illumination of 100mW/cm2.
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溶胶-凝胶法制备ZnO薄膜作为倒置聚合物太阳能电池的电子传输层
本文采用溶胶-凝胶法制备不同摩尔比的乙醇胺氧化锌溶液,低温沉积在ITO衬底上,作为倒置聚合物太阳能电池的电子传输层(ETL)。我们通过详细的分析发现,较少乙醇胺和低温工艺制备的ZnO薄膜,既具有较高的透明度,又具有简单的工艺和控制薄膜表面形貌的特点,并且低温工艺具有柔性,从而在150℃退火10min时将短路密度从7.01提高到8.20mA/cm2。在100mW/cm2的模拟AM1.5G光照下,以聚(3-己基噻吩):[6,6]-苯基C61丁酸甲酯(P3HT:PC61BM)共混膜为活性层的柔性IPSCs的PCE为2.48 ~ 3.17%。
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