Thermopower of ruthenium metallic oxides: Large influence of the spin degeneracy term

S. Hébert, Y. Klein, A. Maignan, J. Hejtmánek, B. Dabrowski
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引用次数: 2

Abstract

The thermoelectric properties of ruthenates have been investigated. All the materials studied here are metallic. Thermopower measurements up to high T show that, even if SrRuO3 is metallic up to 800 K, the Seebeck coefficient of SrRuO3 is constant from 160 K to 800 K, close to +33 muV/K. Different substitutions have been investigated, and the thermopower is almost not affected by the different substitutions, remaining constant from ~200-300 K up to 800K, close to +25-+35 muV/K. The same result is obtained in CaRuO3 and derived compounds. Surprisingly, the value of S is close to the theoretical value calculated from spin entropy term only
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钌金属氧化物的热能:自旋简并项的影响
研究了钌酸盐的热电性质。这里研究的所有材料都是金属。高T以下的热功率测量表明,即使SrRuO3在800k以下是金属,SrRuO3的塞贝克系数在160 K到800 K之间是恒定的,接近+33 muV/K。研究了不同的取代,热功率几乎不受不同取代的影响,在~200-300 K到800K范围内保持恒定,接近+25-+35 muV/K。CaRuO3及其衍生物也得到了同样的结果。令人惊讶的是,S的值接近于仅从自旋熵项计算的理论值
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