R. S. Silva, V. Maggi, J. Z. Ferreira, A. Meneguzzi
{"title":"Anodic protection obtained by applying Smart Paint in Carbon Steel","authors":"R. S. Silva, V. Maggi, J. Z. Ferreira, A. Meneguzzi","doi":"10.5151/CHEMENG-COBEQ2014-0411-25637-144668","DOIUrl":null,"url":null,"abstract":"This work search introduce of a new alternative of organic coating without the presence of hazardous metals and replacement of commercial rectifiers used for protection of oxidized metals by the method of anodic protection. From this, was produced of a Smart Paint (SP), basically composed of a Paint Polyurethane Commercial (PPC) mixed with a 1% of binder de base PAni EB and plasticizer chemically inert 4chloro-3-methylphenol. After, the SP and PPC were applied in plates of carbon steel, with the use of dip coat technique. SP was characterized by thermal analyzes and physicochemical beyond perform electrochemical tests of Cyclic Voltammetry (CV) and Open Circuit Potential (OCP), in aqueous solution 2 mol.L H2SO4. The results obtained allow us to state that the application of the binder to the PPC not significantly alters their physicochemical properties, and that the binder adds the ability to induce the formation or maintenance of protective oxides in oxidized metals exposed to harsh environments.","PeriodicalId":269343,"journal":{"name":"Engenharia Química: princípios fundamentais","volume":"11 1","pages":"0"},"PeriodicalIF":0.0000,"publicationDate":"2014-09-26","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"Engenharia Química: princípios fundamentais","FirstCategoryId":"1085","ListUrlMain":"https://doi.org/10.5151/CHEMENG-COBEQ2014-0411-25637-144668","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"","JCRName":"","Score":null,"Total":0}
引用次数: 0
Abstract
This work search introduce of a new alternative of organic coating without the presence of hazardous metals and replacement of commercial rectifiers used for protection of oxidized metals by the method of anodic protection. From this, was produced of a Smart Paint (SP), basically composed of a Paint Polyurethane Commercial (PPC) mixed with a 1% of binder de base PAni EB and plasticizer chemically inert 4chloro-3-methylphenol. After, the SP and PPC were applied in plates of carbon steel, with the use of dip coat technique. SP was characterized by thermal analyzes and physicochemical beyond perform electrochemical tests of Cyclic Voltammetry (CV) and Open Circuit Potential (OCP), in aqueous solution 2 mol.L H2SO4. The results obtained allow us to state that the application of the binder to the PPC not significantly alters their physicochemical properties, and that the binder adds the ability to induce the formation or maintenance of protective oxides in oxidized metals exposed to harsh environments.
本文研究介绍了一种不含有害金属的有机涂层的新替代品,并取代了用阳极保护方法保护氧化金属的商用整流器。由此,生产了一种智能涂料(SP),主要由涂料聚氨酯商用(PPC)与1%的粘结剂碱性聚苯胺EB和化学惰性增塑剂4氯-3-甲基苯酚混合而成。然后,采用浸涂技术将SP和PPC应用于碳钢板上。在2mol . l H2SO4水溶液中对SP进行了热分析和物理化学表征,并进行了循环伏安(CV)和开路电位(OCP)电化学测试。所获得的结果使我们能够声明,将粘合剂应用于PPC不会显着改变其物理化学性质,并且粘合剂增加了在暴露于恶劣环境的氧化金属中诱导形成或维持保护性氧化物的能力。