A study on Improvement of Electrical and Retention characteristics of Non-volatile Memory with Al2O3 Insulator

Geonju Yoon, Jeongsoo Kim, Donggi Shin, Kumar Mallem, Jinsu Park, Jaemin Kim, Jaehyun Cho, Sangwoo Bae, Jin-Seok Kim, Hyun-Hoo Kim, J. Yi
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引用次数: 2

Abstract

We report the controllable charge (Electron/hole) trapping window layer properties of atomic layer deposited (ALD) aluminum oxide (Al2O3) gate dielectric layer on the Si substrate. Electron/hole blocking mechanism was archived by controlling the Al2O3 composition, band gap and post deposition annealing affect, respectively. The chemical composition of the Al2O3 was confirmed from the X-ray photoelectron spectroscopy analysis. The capacitance-voltage (C-V) characteristic of Al/Al2O3/Si (MOS) metal-oxide-semiconductor structure showed clear accumulation, depletion and inversion regions as-compared with the Al/SiNx/Si MOS devices, respectively, From the C-V curves, the flat band voltage(ΔFB) was shifted accordingly positive and negative with respect to electron/hole trapping effect. In addition, 10 nm AlOx storage layer and SiNx storage layer were compared in the same structure. The 10 nm SiNx storage layer showed a very low retention of 55.1% and the memory window also showed a relatively low value of 2.72V at 18V.
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Al2O3绝缘体改善非易失性存储器电学和保持特性的研究
本文报道了硅衬底上原子层沉积(ALD)氧化铝(Al2O3)栅极介电层的可控电荷(电子/空穴)俘获窗层特性。通过控制Al2O3的组成、带隙和沉积后退火的影响,研究了电子/空穴的阻挡机制。通过x射线光电子能谱分析确定了Al2O3的化学成分。Al/Al2O3/Si (MOS)金属氧化物半导体结构的电容电压(C-V)特性与Al/SiNx/Si MOS器件相比,分别表现出明显的积累区、枯竭区和反转区,从C-V曲线上可以看出,由于电子/空穴捕获效应,平带电压(ΔFB)相应发生了正负偏移。此外,还比较了相同结构下的10 nm AlOx存储层和SiNx存储层。10 nm的SiNx存储层的保留率很低,为55.1%,在18V时的存储窗口也相对较低,为2.72V。
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