Structural, dielectric, electric, and ferroelectric properties of different routes derived of Ba1-xSrxTiO3 (BSTO) ceramic

R. M. Valdes, R. Palai, R. Katiyar
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Abstract

Ba1-xSr3TiO3 (BSTO) is a suitable material for microelectronic device applications due to its high response of the dielectric permittivity an applied electric filed. We have investigated crystal structure, dielectric response, electrical conduction and ferroelectric properties of BSTO. Sol gel and solid state processing were used as routes for the synthesis of BSTO ceramics. The microstructures including grain size and phase analysis have been examined using SEM, X-ray diffraction, and Raman Spectroscopy. The chemical characterization was measured by EDS. From the temperature dependence of measured relative permittivity, loss tangent and, tunability at frequencies between 1 KHz to 1 MHz, the ferroelectric phase transition of BSTO-sg (x=0.4) was observed in ~ 238K, BST-ss (x=0.4) in 267K, and BST-sg & BST-ss (x=0.3) were observed both in ~312K.
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Ba1-xSrxTiO3 (BSTO)陶瓷的结构、介电、电学和铁电性能
Ba1-xSr3TiO3 (BSTO)由于其对外加电场的高介电常数响应而成为微电子器件应用的合适材料。我们研究了BSTO的晶体结构、介电响应、电导率和铁电性能。采用溶胶-凝胶法和固相法制备了BSTO陶瓷。利用扫描电镜、x射线衍射和拉曼光谱分析了其微观结构,包括晶粒尺寸和物相分析。用能谱仪测定了其化学性质。从测量的相对介电常数、损耗正切和1 KHz ~ 1 MHz频率可调性的温度依赖性来看,在~ 238K下观察到BSTO-sg (x=0.4)的铁电相变,在267K下观察到BST-ss (x=0.4)的铁电相变,在~312K下观察到BST-sg和BST-ss (x=0.3)的铁电相变。
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