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2008 17th IEEE International Symposium on the Applications of Ferroelectrics最新文献

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Effects on the dielectric and ferroelectric properties of an O2 atmosphere during sintering of Pb(Fe0.5Nb0.5)O3 ceramics O2气氛对Pb(Fe0.5Nb0.5)O3陶瓷烧结过程中介电性能和铁电性能的影响
Pub Date : 2008-12-02 DOI: 10.1109/ISAF.2008.4693897
Joan Farre-Gisbert, Reynaldo Font-Hernandez, Lourdes Mestres-Vila, M. Martínez-Sarrión, O. Herrera
Multifunctional materials such as the single phase compound Pb(Fe0.5Nb0.5)O3 (PFN), where ferroelectric and magnetic order coexist, are very promising and have great interest from the academic and technological points of view. However, as was established in previous work, the occurrence of Fe2+ and oxygen vacancies originated during the sintering process increase electrical conductivity, dielectric loss, and space-charge accumulation at the grain boundary, all of them detrimental to optimal device performance.1-3 Here, a report on the effects of an O2 atmosphere during the calcination and sintering stages of the preparation process using the traditional ceramic method is presented. A comparative study of structural, morphological and small signal dielectric frequency-temperature response study, where appropriate microstructural and equivalent circuit models were established using the impedance spectroscopy technique is presented. Big differences in the hysteret!ic behavior of the samples prepared in the presence and without the O2 atmosphere were observed and are discussed. The O2 atmosphere improves the dielectric and ferroelectric properties largely, in comparison with previous reports on PFN ceramics where other methods such as sintering in air, Pb atmospheres or fabricated from sol-gel-derived powders were used. 1 O. Raymond et al, J. Appl. Phys. 97, 084107 (2005). 2 O. Raymond et al. J. Appl. Phys. 97, 084108 (2005). 3 O. Raymond et al. J. Appl. Phys. 99, 124101 (2006). This work was partially supported by DGAPA-UNAM Project IN109305-3 and CoNaCyT Projects No. 47714-F and 49986-F. The authors thank E. Aparicio, P. Casillas, I. Gradilla, and J. Peralta for their technical assistance.
以铁电序与磁序共存的单相化合物Pb(Fe0.5Nb0.5)O3 (PFN)为代表的多功能材料具有广阔的应用前景和广泛的技术应用前景。然而,正如之前的工作所确定的那样,在烧结过程中产生的Fe2+和氧空位增加了电导率、介电损耗和晶界的空间电荷积累,所有这些都不利于器件的最佳性能。1-3本文介绍了使用传统陶瓷方法制备过程中,在煅烧和烧结阶段O2气氛的影响。利用阻抗谱技术建立了相应的微结构和等效电路模型,对结构、形态和小信号介质频率-温度响应进行了对比研究。歇斯底里有很大的不同!对制备的样品在有氧气氛和无氧气氛下的ic行为进行了观察和讨论。与之前报道的PFN陶瓷相比,O2气氛大大提高了介电和铁电性能,其中其他方法如在空气中烧结,铅气氛或由溶胶-凝胶衍生的粉末制备。[1]李建平等。物理学报,97,084(2005)。[2]雷蒙德等。j:。物理学报,97,084108(2005)。3雷蒙德等。j:。物理学报,1999,12(1)(2006)。这项工作得到了DGAPA-UNAM项目IN109305-3和CoNaCyT项目No. 47714-F和49986-F的部分支持。作者感谢E. Aparicio、P. Casillas、I. Gradilla和J. Peralta提供的技术援助。
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引用次数: 0
High-frequency (>100MHz) PZT thick film transducers and Kerfless arrays 高频(>100MHz) PZT厚膜换能器和无kerless阵列
Pub Date : 2008-12-02 DOI: 10.1109/ISAF.2008.4693881
D. Wu, Q. Zhou, B. Zhu, K. Shung, F. Djuth, C. G. Liu
This paper presents the latest development of high-frequency (>100MHz) PZT film ultrasonic transducers and kerfless arrays. PZT thick films of 12 ¿m in thickness were fabricated with a spin-coating method. The films were found to have a remanent polarization of 33 ¿C/cm2 and a coercive field Ec of 70 kV/cm. High-frequency (120MHz) single element transducers and a kerfless array were successfully fabricated with these films. The transducer and array have ¿6dB bandwidth of 40% without matching, and 60% with a layer of parylene as the matching layer. The single element transducer was found to have an axial resolution of 20¿m and lateral resolution of 100¿m. Ultrasonic images of a porcine eye were also successfully acquired with the single element transducer. Kerfless array imaging is onging.
本文介绍了高频(>100MHz) PZT薄膜超声换能器和无角阵列的最新进展。采用旋涂法制备了厚度为12¿m的PZT厚膜。发现薄膜的残余极化为33¿C/cm2,矫顽力场Ec为70 kV/cm。利用这些薄膜成功地制作了高频(120MHz)单元件换能器和无角阵列。换能器与阵列的带宽不匹配时为40%,有一层聚对二甲苯作为匹配层时为60%。单元件传感器的轴向分辨率为20微米,横向分辨率为100微米。用单元件换能器也成功地获得了猪眼的超声图像。无角阵列成像正在进行中。
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引用次数: 4
Size effect of barium titanate and MLCCs in the next generation 下一代钛酸钡和mlcc的尺寸效应
Pub Date : 2008-12-02 DOI: 10.1109/ISAF.2008.4693883
T. Tsurumi, T. Hoshina, K. Takizawa, H. Kakemoto
The size effect of BaTiO3 (BTO) is the most important issue to design the high-capacitance MLCCs in the next generation. In the size effect of BTO ceramics and powders, the maxima of the permittivity were observed at certain grain size and the particle size. The permittivity maximum in the ceramics was due to the domain wall contribution, while that in the powders related with the complex structure of the BTO powders. Computer simulation technique was developed to predict the limit of capacitance density of the multilayer ceramics capacitors (MLCCs) produced by the current technology.
BaTiO3 (BTO)的尺寸效应是设计下一代高电容mlcc最重要的问题。在BTO陶瓷和粉末的尺寸效应中,介电常数在一定的晶粒尺寸和颗粒尺寸下达到最大值。陶瓷中的介电常数最大值是由于畴壁的贡献,而粉末中的介电常数最大值则与BTO粉末的复杂结构有关。采用计算机模拟技术对现有工艺生产的多层陶瓷电容器的电容密度极限进行了预测。
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引用次数: 1
Broadband permittivity measurements of thin-film ferroelectrics to 40 GHz 40 GHz的薄膜铁电体宽带介电常数测量
Pub Date : 2008-12-02 DOI: 10.1109/ISAF.2008.4693752
N. Orloff, J. Booth, M. Murakami, I. Takeuchi
We demonstrate a novel experimental technique to measure the complex permittivity of dielectric thin films over the frequency range from 100 Hz to 40 GHz. We apply this technique to determine the broadband permittivity for ferroelectric thin films such as PbTiO3 at room temperature. We discuss the value of such frequency-dependent measurements for determining the dielectric response of ferroelectric thin films at finite frequencies.
我们展示了一种新的实验技术来测量介电薄膜在100 Hz到40 GHz频率范围内的复介电常数。我们应用该技术测定了铁电薄膜(如PbTiO3)在室温下的宽带介电常数。我们讨论了这种频率相关测量在确定铁电薄膜在有限频率下的介电响应的价值。
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引用次数: 1
Ferroelectric based technologies for high power RF and accelerator applications 高功率射频和加速器应用的铁电技术
Pub Date : 2008-12-02 DOI: 10.1109/ISAF.2008.4693759
A. Kanareykin, S. Kazakov, E. Nansheva, A. Tagantsev, V. Yakovlev
We present recent results on development of BST based ferroelectric compositions synthesized for use in high power technology components for X-band and Ka-band RF systems and offer significant advantages for high power RF manipulation in the 300¿1000 MHz frequency range as well. These low loss ferroelectric materials can be used as key elements of both tuning and phase shifting components. Fast, electrically-controlled ferroelectric RF switches and phase shifters are under development for different accelerator applications in X, Ka and L - frequency bands either. The exact design of such a devise depends on the electrical parameters of particular ferroelectric material to be used, namely its dielectric constant, loss tangent and tunability. We have identified BST based ferroelectric-oxide compounds as suitable materials for a fast electrically-controlled 700 MHz, 50 kW tuner for Brookhaven National Lab and for high-power fast RF phase shifters to be used for SNS, Oakridge National Lab vector modulation applications. The bulk ferroelectric based phase shifter will allow coupling adjustment and control of the power consumption during the process of SC cavity filling, which is of great importance for the Intl. Linear Collider (ILC) program. New methods were developed in order to measure parameters of large ferroelectric components. The results of measurements are presented.
我们介绍了基于BST的铁电组合物的最新研究成果,该组合物可用于x波段和ka波段射频系统的高功率技术组件,并为300 - 1000 MHz频率范围内的高功率射频操作提供了显着优势。这些低损耗铁电材料可作为调谐元件和相移元件的关键元件。快速,电控铁电射频开关和移相器正在开发用于X, Ka和L频段的不同加速器应用。这种装置的精确设计取决于所使用的特定铁电材料的电学参数,即介电常数、损耗正切和可调性。我们已经确定了基于BST的铁电氧化物化合物是布鲁克海文国家实验室的快速电动控制700 MHz, 50 kW调谐器和用于SNS, Oakridge国家实验室矢量调制应用的高功率快速RF移相器的合适材料。基于块体铁电的移相器可以对SC空腔填充过程中的功耗进行耦合调节和控制,这对国际上具有重要意义。线性对撞机(ILC)程序。研究了大型铁电元件参数测量的新方法。给出了测量结果。
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引用次数: 0
Bismuth niobate glass-ceramics for dielectrically-loaded microwave antenna applications 介电负载微波天线用铌酸铋微晶玻璃
Pub Date : 2008-12-02 DOI: 10.1109/ISAF.2008.4693751
M. Mirsaneh, B. Zalinska, O. Leisten, I. Reaney
Dielectrically-loaded quadrifillar-helix (D-LQH) antennas are used in applications such as global positioning systems and satellite radio where high gain is required for direct communication with satellites. The current generation of D-LQH antenna are made from hollow cylinders of medium permittivity (15Ç,ßå¿rÇß80), high quality factor (Qf), temperature stable ceramics coated with a helical Cu metallisation. To reduce the processing costs of the ceramic core, a castable bismuth niobate glass-ceramics (30% Bi2O3, 30% Nb2O5, 30% B2O3 and 10% SiO2, in mol%) has been developed. On crystallisation at 600°C, a nano-dendritic, pyrochlore-structured phase evolves with å¿r = 41 and Qf = 226. This phase is unstable at >700°C and is initially replaced by triclinic-BiNbO4 (BN) (700 Ç¿Ï 900°C) and then by orthorhombic BN (>900°C). Optimum properties for antenna core applications occur at 920°C heat treatment with å¿r = 15, Qf = 8000 GHz at which point the temperature ! coefficient of resonant frequency is ¿60 MK-1.
介质负载的四轴螺旋(D-LQH)天线用于全球定位系统和卫星无线电等需要高增益与卫星直接通信的应用中。当前一代的D-LQH天线由中空圆柱体制成,具有中等介电常数(15Ç,ß ¿rÇß80),高质量因子(Qf),温度稳定的陶瓷,并涂有螺旋Cu金属化。为了降低陶瓷芯的加工成本,研制了一种可浇注的铌酸铋微晶玻璃(30% Bi2O3, 30% Nb2O5, 30% B2O3, 10% SiO2, mol%)。在600℃结晶时,形成一种纳米枝晶、焦绿结构的相,其¿r = 41, Qf = 226。该相在>700°C时不稳定,最初由三斜型binbo4 (BN) (700 Ç¿Ï 900°C)取代,然后由正交BN(>900°C)取代。天线核心应用的最佳性能发生在920°C的热处理,¿r = 15, Qf = 8000 GHz,此时的温度为:谐振频率系数为¿60 MK-1。
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引用次数: 1
Dielectric properties and microstructure of CaCu3Ti4-xMnxO12 ceramics cuu3ti4 - xmnxo12陶瓷的介电性能和微观结构
Pub Date : 2008-12-02 DOI: 10.1109/ISAF.2008.4693905
W. Makcharoen, J. Tontrakoon, P. Thavornyutikarn, D. Cann, T. Tunkasiri
In this work, we have reported the dielectric properties and microstructure of the Mn doped CaCu3Ti4O12 (CCTO) ceramics. The conventional solid-state reaction was employed. By the partial Mn -for Ti substitution, the dielectric loss was suppressed remarkably while the dielectric constant (¿r) still remains high. The sample CaCu3Ti3.76Mn0.24O12 exhibits a high ¿r over 1200 and a low dielectric loss below 0.06 at room temperature. Furthermore, the ¿r value of this sample shows rather independent with temperature. SEM micrographs show that the sample is dense (¿ 90% of theoretical density) and the grain size of the samples was gradually reduced with increasing x. This CaCu3Ti4-xMnxO12 system is believed to be a promising candidate for capacitor applications.
本文报道了Mn掺杂ccu3ti4o12 (CCTO)陶瓷的介电性能和微观结构。采用传统的固相反应。通过部分Mn取代Ti,在介电常数(¿r)仍然很高的情况下,介质损耗得到了明显的抑制。样品CaCu3Ti3.76Mn0.24O12在室温下具有高于1200的高¿r和低于0.06的低介电损耗。此外,该样品的¿r值与温度无关。SEM显微图显示样品致密(理论密度的90%),样品的晶粒尺寸随着x的增加而逐渐减小。该CaCu3Ti4-xMnxO12体系被认为是电容器应用的有希望的候选者。
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引用次数: 4
Structural and dielectric properties of BaTiO3 - BiScO3 ceramics BaTiO3 - BiScO3陶瓷的结构和介电性能
Pub Date : 2008-12-02 DOI: 10.1109/ISAF.2008.4693886
H. Ogihara, C. Randall, S. Trolier-McKinstry
The structural and dielectric properties of bulk (1¿x) BaTiO3¿x BiScO3 (x = 0 ¿ 0.6) ceramics were investigated to acquire a better understanding of the binary system, including determination of the phase diagram, dielectric properties, and the difference in roles of Bi and BiScO3 doping on BaTiO3. The solubility limit for BiScO3 into the BaTiO3 perovskite structure was determined to be about x = 0.4, which was much higher than the solubility of Bi alone. A structural change from tetragonal to pseudocubic was observed at about x = 0.05 ¿ 0.1 at room temperature. Dielectric measurements revealed the gradual change from typical ferroelectric behavior in pure BaTiO3 to a highly diffusive and dispersive relaxor behavior from 10 to 40 mol% BiScO3. Several of the compositions showed high permittivities (approximately 1000) with low temperature coefficients of capacitance.
为了更好地理解二元体系,研究了大块(1¿x) BaTiO3¿x BiScO3 (x = 0¿0.6)陶瓷的结构和介电性能,包括确定相图、介电性能以及Bi和BiScO3掺杂对BaTiO3的不同作用。测定了BiScO3在BaTiO3钙钛矿结构中的溶解度极限约为x = 0.4,远高于Bi的溶解度。在室温下,当x = 0.05 ~ 0.1时,观察到从四边形到伪圆柱形的结构变化。介电测量表明,从纯BaTiO3的典型铁电行为逐渐转变为10 ~ 40 mol% BaTiO3的高扩散和色散弛豫行为。几种组合物表现出高介电常数(约1000)和低电容温度系数。
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引用次数: 0
Combining energy harvesting and power management for a complete wireless sensor power solution 结合能量收集和电源管理为一个完整的无线传感器电源解决方案
Pub Date : 2008-12-02 DOI: 10.1109/ISAF.2008.4693940
C. Lakeman, P. Fleig, J. T. Trainor, Mark A. Fuge
Wireless sensors provide solutions to otherwise intractable problems where it is impractical to deploy wired sensors. One of the biggest challenges facing wireless sensors is power. Advances in power management and battery technologies may soon enable three year life from primary batteries, but will require stringent control over sensor operation that, in many applications, will place unacceptable limits on the performance of parameters such as data rate or transmission range. Energy harvesting provides a solution to these problems, but tends to be limited by the inherent low and fluctuating level of ambient energy. In this presentation we will demonstrate a system that combines smart, ultra-low power charge management circuitry and electrochemical energy storage that is compatible with any energy harvesting technology. This building block is essential for realizing a power system that can replace batteries in end-user systems providing the benefits of energy harvesting technology while mitigating the drawbacks.
无线传感器为部署有线传感器不切实际的棘手问题提供了解决方案。无线传感器面临的最大挑战之一是功率。电源管理和电池技术的进步可能很快就会使原电池的使用寿命达到三年,但这需要对传感器的操作进行严格控制,在许多应用中,这将对数据速率或传输范围等参数的性能产生不可接受的限制。能量收集为这些问题提供了解决方案,但往往受到环境能量固有的低和波动水平的限制。在本次演讲中,我们将展示一个结合智能、超低功耗充电管理电路和电化学能量存储的系统,该系统与任何能量收集技术兼容。这种构建模块对于实现一种可以在终端用户系统中取代电池的电力系统至关重要,它提供了能量收集技术的优点,同时减轻了缺点。
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引用次数: 0
Tunable dielectrics for microwave applications 微波应用的可调谐电介质
Pub Date : 2008-12-02 DOI: 10.1109/ISAF.2008.4693753
A. Giere, Y. Zheng, H. Maune, M. Sazegar, F. Paul, X. Zhou, J. Binder, S. Muller, R. Jakoby
This paper gives a short introduction into tunable dielectrics for microwave applications based on nematic liquid crystal and Barium-Strontium-Titanate (BST) thin- and thick-films. Due to their tuning voltage dependent electromagnetic properties, both are very promising material candidates for tunable passives in the microwave and millimeter-wave regions. For applications, such as frequency-agile communications and sensor systems we illustrate the challenges of optimization BST films based on a multi-scale view for material, processing, device and application design.
本文简要介绍了以向列液晶和钛酸钡锶(BST)薄膜和厚膜为基础的微波可调谐介质。由于其与调谐电压相关的电磁特性,两者都是微波和毫米波区域中非常有前途的可调谐无源材料候选材料。对于诸如频率敏捷通信和传感器系统等应用,我们说明了基于材料,加工,设备和应用设计的多尺度视图优化BST薄膜的挑战。
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引用次数: 9
期刊
2008 17th IEEE International Symposium on the Applications of Ferroelectrics
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