A Study on AlCu with ALPS Al and Glue layer on Electromigration

Shih-Hui Lin
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Abstract

It has been reported, that EM lifetime of Ti/Al-Cu structure is shorter than that of Ti/TiN/Al-Cu structure. Our study shows that the lifetime of Ti/ALPS Al-Cu structure is better than Ti/TiN/ALPS Al-Cu. In this paper, we will discuss the effect of the Glue layer -Ti/TiN & Ti, and the effect of the AlCu processes-Hot Al and ALPS/Hot Al to explain the main reasons. After the study, we found Ti /ALPS/Hot Al-Cu has the best EM lifetime and we believe it’s due to (1) The ALPS process has less Cu precipitation at the interface between Al and Ti/TiN, which makes Cu more concentrated in the AlCu layer (2) The Glue layer of Ti forms TiAl3, and these intermetallic compounds changes the AlCu ratio. The Al atomic ratio decreases, while the Cu atomic ratio increases .The formation of Ti3Al intermetallic compounds increased the Cu concentration in the grain boundary of AlCu metal line and affected the EM result.
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AlCu的电迁移性能研究
据报道,Ti/Al-Cu结构的EM寿命比Ti/TiN/Al-Cu结构的EM寿命短。研究表明,Ti/ALPS Al-Cu结构的寿命优于Ti/TiN/ALPS Al-Cu结构。在本文中,我们将讨论胶层-Ti/TiN和Ti的影响,以及AlCu工艺-Hot Al和ALPS/Hot Al的影响,以说明主要原因。研究发现,Ti/ ALPS/Hot Al-Cu具有最佳的EM寿命,认为这是由于(1)ALPS工艺在Al和Ti/TiN界面处Cu析出较少,使得Cu更集中在AlCu层中(2)Ti的胶层形成TiAl3,这些金属间化合物改变了AlCu比。Al原子比减小,Cu原子比增大,Ti3Al金属间化合物的形成增加了AlCu金属线晶界处的Cu浓度,影响了EM结果。
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