Effect of plastic pyrolysis oil and its blends with diesel on Cetane Index

Rupesh Lal Karn, S. Aryal, Barsha Neupane, Kushal Bhattarai, Laxman Palikhel
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Abstract

Availability and higher gasoline price have attracted the attention of researchers towards alternative fuels. Plastic is produced from the byproduct of gasoline products, which possesses a higher possibility of recycling the waste plastic as an alternative fuel. Research conducted on plastic fuel shows that a diesel engine can run with 100% plastic oil. The present work is focused on the effect of distilled plastic oil on the cetane index as the cetane index is a major fuel property of diesel that affects the ignition quality and exhaust emissions of the engine. For the measurement of the cetane index, two standards are followed and they are ASTM D4737 and ASTM D976. It is found that Crude plastic oil produced from thermal pyrolysis of waste plastic possesses a wide variety of hydrocarbon i.e. lower to higher hydrocarbon. From the fractional distillation of crude plastic oil at three temperature ranges 200◦C, 290◦C and up to the final boiling point, it gave petrol grade oil and diesel grade oil (both low and high grade). Also, it was found that the recovery of distilled high-grade plastic oil is higher than other distilled crude plastic oil. Along with this, crude plastic oil, as well as high-grade plastic oil, have a higher cetane index than the diesel available in the market. Similarly, blending diesel with high-grade plastic oil up to 20% by volume and with low-grade plastic oil up to 10% by volume increases the cetane index of fuel.
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塑料热解油及其与柴油共混物对十六烷指数的影响
可获得性和较高的汽油价格吸引了研究人员对替代燃料的关注。塑料是由汽油产品的副产品生产的,它具有更高的可能性回收废塑料作为替代燃料。对塑料燃料的研究表明,柴油发动机可以使用100%的塑料油。十六烷指数是柴油的主要燃料性质,直接影响发动机的点火质量和废气排放,因此本文主要研究了蒸馏塑料油对十六烷指数的影响。十六烷指数的测量遵循ASTM D4737和ASTM D976两个标准。研究发现,废塑料热裂解生产的塑料粗油烃类种类繁多,从低烃到高烃。从粗塑料油的分馏在三个温度范围200◦C, 290◦C和最终沸点,它给出了汽油级油和柴油级油(低和高等级)。此外,还发现蒸馏后的高档塑料油的回收率高于其他蒸馏后的粗塑料油。与此同时,粗塑料油和高档塑料油的十六烷指数高于市场上可买到的柴油。同样,将柴油与高达20%(体积)的高级塑料油和高达10%(体积)的低级塑料油混合,会增加燃料的十六烷指数。
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