Effects of Alloying Elements on the Microstructure and Mechanical Properties of Novel α+β Dual-Phase Ti-Nb-Ta-Zr Alloys

Tingan Zhang, Daixiu Wei, Liqiang Wang, Eryi Lu, Wen Wang, Kuai-She Wang, Xiaoqing Li, Lai‐Chang Zhang, H. Kato, Weijie Lu
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Abstract

A series of novel α+β dual-phase Ti-Nb-Ta-Zr (Ti-(3, 5) wt.% Nb-(2, 10, 13) wt.% Ta- 2 wt.% Zr) alloys with low elastic modulus were designed by reducing the stability of β-phase under the guidelines of ab initio calculations and d-electronic theory. The alloys exhibit typical characteristics of α+β dual-phase microstructure. Among the alloys, Ti-3Nb-13Ta-2Zr alloy shows the lowest Young’s modulus (61 GPa) with highest ultimate tensile strength (779 MPa), mainly attributed to the combination of α + β dual-phase structure with stress-induced α" martensite. Moreover, {0001} α α and {001} β β textures also contribute to the reduction of elastic modulus of the alloy. Atom probe tomography analysis reveals that the elemental partitioning between α and β leads to the enrichment of solutes (Nb, Ta, Zr) in the β phase, and the elements distribution in the β phase is uneven.
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合金元素对新型α+β双相Ti-Nb-Ta-Zr合金组织和力学性能的影响
采用从头计算和d电子理论,通过降低β相的稳定性,设计了一系列具有低弹性模量的新型α+β双相Ti-Nb-Ta-Zr (Ti-(3,5) wt.% Nb-(2,10,13) wt.% Ta- 2wt .% Zr)合金。合金具有典型的α+β双相组织特征。其中,Ti-3Nb-13Ta-2Zr合金的杨氏模量最低(61 GPa),极限抗拉强度最高(779 MPa),这主要是由于α + β双相组织与应力诱导的α”马氏体结合所致。{0001} α α和{001}β β织构也导致合金弹性模量的降低。原子探针层析分析表明,α和β之间的元素分配导致溶质(Nb、Ta、Zr)在β相中富集,且元素在β相中分布不均匀。
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