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Genesis of Plasticity-Induced Serrated Metal Flow in Medium-Mn Steel 中锰钢中塑性诱导的锯齿状金属流动的成因
Pub Date : 2022-06-01 DOI: 10.2139/ssrn.3742930
N. Bhowmik, Saroj Kumar Ghosh, S. Mandal, A. Haldar, P. Chattopadhyay
An excellent strength-ductility combination offered by martensite-austenite microstructure in medium-Mn steels draws special attention for automotive applications. However, yielding of the steel is often compromised in the form of serration, with a jerky metal flow and deformation banding, by the reason yet to be settled. Thus as per the practice, a hot-rolled sheet after intercritical annealing at 650 °C is subjected to the current investigation. The intercritical annealing reveals an undissolved-unoccupied state attained by carbon, which readily interacts with the sample dislocations introduced in the microstructure during the prior processing. The interaction forms Cottrell atmospheres at annealing temperature rather than at room temperature as enumerated in metal plasticity theory, and hence, finds the clue for hitherto unexplored mechanism of dynamic strain aging. Accordingly, when fresh dislocations intercept barriers laid by the carbon-dislocation aggregates into clusters in advance, the interaction triggers serration for the proposed mechanism.
中锰钢的马氏体-奥氏体显微组织提供了优异的强度-塑性组合,引起了汽车应用的特别关注。然而,钢的屈服往往以锯齿形的形式受到损害,金属流动和变形带不稳定,原因尚未解决。因此,根据惯例,在650°C下进行临界间退火后的热轧薄板进行了当前的研究。临界间退火揭示了碳获得的未溶解-未占据状态,这很容易与先前处理过程中引入的微观结构中的样品位错相互作用。这种相互作用在退火温度下而不是在金属塑性理论中所列举的室温下形成Cottrell气氛,从而为迄今尚未探索的动态应变时效机制找到了线索。因此,当新的位错拦截碳位错预先聚集成簇的屏障时,相互作用触发了所提出机制的锯齿作用。
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引用次数: 4
Tuning Mechanical Properties of High Entropy Alloys by Electro-Pulsing Method 电脉冲法调谐高熵合金力学性能
Pub Date : 2022-01-01 DOI: 10.2139/ssrn.3932309
N. Wang, R. K. Nutor, Y.X. Li, Q. Cao, S. Ding, X.D. Wang, D.X. Zhang, J. Jiang
The single-phase face-centered cubic (FCC) high entropy alloys (HEAs) with remarkable ductility but lower strength, limiting the engineering application in a wide range. The ductility-strength trade-off could be addressed by tuning the constituent and chemical composition to lower stacking fault energy (SFE) and introduce additional strain-hardening strategies. In this work, a series of non-equiatomic (Co 40 Fe 25 Cr 20 Ni 15 ) 95 Al 5 HEAs annealed by flash electro-pulsing treatments at different voltages, was prepared with the incorporation of deformation twining during plastic deformation. The 130 V-annealed sample demonstrated a good combination of tensile strength of 0.96 GPa and ductility of 16.5%, while the 150 V-annealed alloy showed dramatically increased ductility of 49.2%. The higher Hall-Petch coefficient k H ( K σy ) value of 341.6 (828.8) and the thinner deformation twins spacing was responsible for the improved tensile strength for 130 V-samples. Moreover, more stacking faults and deformation twins in 150 V-sample accommodated more plastic and delayed the fracture, resulting increased ductility. This work provides a fast-effective method to tune the mechanical properties of non-equiatomic HEAs by adjusting the annealing voltage and achieved in a minute, which might open the avenue for future industrial application.
单相面心立方(FCC)高熵合金(HEAs)塑性好,但强度较低,限制了其在工程上的广泛应用。可以通过调整成分和化学成分来降低层错能(SFE)并引入额外的应变硬化策略来解决延展性和强度之间的权衡。本文制备了一系列非等原子(Co 40 Fe 25 Cr 20 Ni 15) 95 Al 5 HEAs,并在塑性变形过程中掺入变形缠绕。经130 v退火后,合金的抗拉强度为0.96 GPa,延展性为16.5%,而经150 v退火后,合金的延展性显著提高,达到49.2%。增大的Hall-Petch系数k H (k σy)值为341.6(828.8),减小变形孪晶间距是提高130 v试样抗拉强度的主要原因。另外,150v试样中更多的层错和变形孪晶容纳了更多的塑性,延迟了断裂,从而提高了延性。本工作提供了一种快速有效的方法,通过调整退火电压来调整非等原子HEAs的机械性能,并在一分钟内实现,为未来的工业应用开辟了道路。
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引用次数: 1
Compression Fatigue Properties and Damage Mechanisms of a Bioinspired Nacre-Like Ceramic-Polymer Composite 仿生类珍珠陶瓷-聚合物复合材料的压缩疲劳性能及损伤机理
Pub Date : 2021-10-01 DOI: 10.2139/ssrn.3860384
Guoqi Tan, Qin Yu, Zengqian Liu, Xuegang Wang, Mingyang Zhang, Yanyan Liu, Zhefeng Zhang, R. Ritchie
Abstract Fatigue resistance is invariably critical for structural materials, but is rarely considered in the development of new bioinspired materials. Here the fatigue behavior and damage mechanisms of a nacre-like ceramic (yttria-stabilized zirconia) - polymer (polymethyl methacrylate) composite, which resembles human tooth enamel in its stiffness and hardness, were investigated under cyclic compression to simulate potential service conditions. The composite has a brick-and-mortar structure which exhibits a staircase-like fracture behavior; it displays a transition in cracking mode from the fracture of the ceramic bricks to separation along the inter-brick polymer phase with increasing stress amplitude. The nacre-like structure functions to induce crack deflection, increase the roughness of the crack surfaces, and promote the mutual sliding between bricks during fracture; this results in high fatigue resistance, which enhances the potential of this composite for dental applications.
摘要:抗疲劳性是结构材料的关键,但在新型生物材料的开发中很少被考虑。本文研究了一种类似人类牙釉质刚度和硬度的纳米状陶瓷(氧化钇稳定氧化锆)-聚合物(聚甲基丙烯酸甲酯)复合材料在循环压缩下的疲劳行为和损伤机制,以模拟潜在的使用条件。复合材料具有砂浆结构,呈现阶梯状断裂行为;随着应力幅值的增大,裂纹模式由砖的断裂向砖间聚合物相的分离转变。裂纹状结构的作用是诱导裂纹偏转,增加裂纹表面的粗糙度,促进断裂时砖间的相互滑动;这导致了高抗疲劳性,增强了这种复合材料在牙科应用中的潜力。
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引用次数: 16
Grain Size Altering Yielding Mechanisms in Ultrafine Grained High-Mn Austenitic Steel: Advanced TEM Investigations 超细晶高锰奥氏体钢晶粒尺寸改变屈服机制:先进的透射电镜研究
Pub Date : 2021-09-30 DOI: 10.2139/ssrn.3681163
Chang-Yu Hung, Y. Bai, N. Tsuji, M. Murayama
Abstract The underlying mechanism of discontinuous yielding behavior in an ultrafine-grained (UFG) Fe-31Mn-3Al-3Si (wt.%) austenitic TWIP steel was investigated by the use of advanced TEM technique with taking the plastic deformation mechanisms and their correlation with grains size near the macroscopic yield point into account. Typical yield drop mechanisms such as the dislocation locking by the Cottrell atmosphere due to the presence of interstitial impurities cannot explain the origin of this phenomenon in the UFG high-Mn austenitic TWIP steel. Here, we experimentally revealed that the plastic deformation mechanisms in the early stage of deformation, around the macroscopic yield point, show an obvious association with grain size. More specifically, the main mechanism shifts from the conventional slip in grain interior to twinning nucleated from grain boundaries with decreasing the grain size down to less than 1 μm. Our observation indicates that the grain size dependent deformation mechanisms transition is also deeply associated with the discontinuous yielding behavior as it could govern the changes in the grain interior dislocation density of mobile dislocations around the macroscopic yield point.
摘要采用先进的透射电镜技术研究了超细晶(UFG) Fe-31Mn-3Al-3Si (wt.%)奥氏体TWIP钢的不连续屈服行为的潜在机制,并考虑了宏观屈服点附近的塑性变形机制及其与晶粒尺寸的相关性。典型的屈服下降机制,如由于间隙杂质的存在而引起的Cottrell气氛的位错锁定,不能解释UFG高mn奥氏体TWIP钢中这种现象的起源。在此,我们通过实验揭示了变形早期,在宏观屈服点附近的塑性变形机制与晶粒尺寸有明显的关联。更具体地说,随着晶粒尺寸减小到小于1 μm,主要机制由传统的晶粒内部滑移转变为晶界成核孪晶。我们的观察表明,晶粒尺寸依赖的变形机制转变也与不连续屈服行为密切相关,因为它可以控制宏观屈服点周围移动位错的晶粒内部位错密度的变化。
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引用次数: 25
Microstructure and Deformation Behaviour of Austenitic Low-Density Steels: The Defining Role of B2 Intermetallic Phase 奥氏体低密度钢的组织和变形行为:B2金属间相的决定性作用
Pub Date : 2021-08-24 DOI: 10.2139/ssrn.3831019
B. Mishra, R. Sarkar, Vajinder Singh, A. Mukhopadhyay, Rohit T. Mathew, V. Madhu, M. Prasad
Abstract The feasibility of significant weight reduction in conjunction with the superior strength-ductility combination makes Fe-Mn-Al-C-based steels the candidate material for automotive and structural applications. The alloy chemistry and processing conditions influence the microstructure in low-density steels (LDS); however, their role in deformation behaviour is not fully understood. In the present study, three different austenitic LDS grades viz. Fe-28Mn-9Al-0.9C, Fe-28Mn-9Al-5Ni-0.9C and Fe-15Mn-9Al-5Ni-0.9C alloys in hot-rolled conditions were used for evaluating the role of secondary phases, especially B2 ordered Fe(Ni)Al phase on deformation characteristics. Ni-free LDS microstructure consisted of the γ-matrix with fine κ-carbides, whereas Ni containing low Mn alloy possessed coarser κ-carbides along with B2 in both bamboo-like stringer and polygonal particle morphology in the γ-matrix. The B2 containing alloy exhibited higher strength with reduced tensile ductility than the B2-free alloy. Hardness of the γ-matrix and B2 phase were similar with B2 grains exhibiting distinct pop-in events in the nanoindentation curves indicating incipient plasticity. The γ-matrix and B2 co-deform near yield, and a favourable orientation relationship (OR) between the γ-matrix and B2 facilitated easy slip transfer, while the non-favourable OR controlled ductility by strain accumulation and B2-cracking. The differences in the strain hardening behaviour of B2-free and B2 containing alloys were elucidated based on the changes in dislocation substructure evolution examined by an automated crystal orientation mapping in electron microscopy.
fe - mn - al - c基钢显著减轻重量的可行性,加上其优越的强度-延展性组合,使其成为汽车和结构应用的候选材料。合金化学成分和加工条件对低密度钢组织的影响然而,它们在变形行为中的作用尚不完全清楚。本研究采用Fe- 28mn - 9al -0.9 c、Fe- 28mn - 9al - 5ni -0.9 c和Fe- 15mn - 9al - 5ni -0.9 c三种不同奥氏体LDS合金热轧条件下,评价了二次相,特别是B2有序Fe(Ni)Al相对变形特性的影响。无Ni合金的LDS组织由γ-基体中含有细小的κ-碳化物组成,而含Ni合金的低Mn合金在γ-基体中含有较粗的κ-碳化物和B2,呈竹状弦状,呈多边形颗粒形态。与不含B2的合金相比,含B2的合金具有更高的强度,但拉伸延展性降低。γ-基体和B2相的硬度与B2晶粒相似,在纳米压痕曲线上表现出明显的弹出事件,表明塑性初期。γ-基体与B2在屈服附近共变形,γ-基体与B2之间良好的取向关系(OR)有利于滑移传递,而不利的取向关系通过应变积累和B2开裂控制塑性。利用电子显微镜的自动晶体取向图分析了位错亚结构演变的变化,阐明了无B2合金和含B2合金应变硬化行为的差异。
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引用次数: 9
Enthalpy of Collagen Interfibrillar Bonds in Fetal Membranes 胎膜中胶原纤维间键的焓
Pub Date : 2021-07-10 DOI: 10.2139/ssrn.3592060
Y. Marom, S. Gengrinovitch, E. Shalev, D. Shilo
During pregnancy, the fetal membrane (FM) is subjected to mechanical stretching that may result in preterm labor. The structural integrity of the FM is maintained by its collagenous layer. The disconnection and reconnection of molecular bonds between collagen fibrils are the fundamental processes that govern the irreversible mechanical and supermolecular changes in the FM. Here, we study the activation enthalpy of interfibrillar bonds in ex-vivo human FM. We analyze the strain-rate and temperature dependence of the irreversible deformations in FM subjected to inflation tests, which apply mechanical conditions similar to those experienced by the FM prior to and during the initiation of labor contractions. The obtained activation enthalpy of interfibrillar bonds matches the typical enthalpy values of polyvalent ionic bonds, implying on another important role that ions like Ca and Mg may play in the gestation and labor.
在怀孕期间,胎膜(FM)受到机械拉伸,可能导致早产。FM的结构完整性是由其胶原层维持的。胶原原纤维之间分子键的断开和重连接是控制FM中不可逆的力学和超分子变化的基本过程。在此,我们研究了离体人FM纤维间键的激活焓。我们分析了不可逆变形的应变率和温度依赖的FM经受膨胀试验,其中应用的机械条件类似于那些经历的FM之前和在劳动收缩的开始。得到的纤维间键的活化焓值与典型的多价离子键的焓值相匹配,暗示了Ca和Mg等离子在妊娠和分娩过程中可能发挥的另一个重要作用。
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引用次数: 1
Cold Dwell Behaviour of Ti6Al Alloy: Understanding Load Shedding Using Digital Image Correlation and Crystal Plasticity Simulations Ti6Al合金的冷居住行为:利用数字图像相关和晶体塑性模拟来理解负载脱落
Pub Date : 2021-06-23 DOI: 10.2139/ssrn.3862135
Y. Xiong, N. Grilli, Phani S. Karamched, B. Li, E. Tarleton, A. Wilkinson
Digital image correlation (DIC) and crystal plasticity simulation were utilised to study cold dwell behaviour in a coarse grain Ti-6Al alloy at 3 different temperatures up to 230 °C. Strains extracted from large volume grains were measured during creep by DIC and were used to calibrate the crystal plasticity model. The values of critical resolved shear stresses (CRSS) of the two main slip systems (basal and prismatic) were determined as a function of temperature. Stress along paths across the boundaries of two grain pairs, (1) a `rogue' grain pair and (2) a `non-rogue' grain pair, were determined at different temperatures. Load shedding was observed in the `rogue' grain pair, where a stress increment during the creep period was found in the `hard' grain. At elevated temperatures, 120 °C was found to be the worst case scenario as the stress difference at the grain boundaries of these two grain pairs were found to be the largest among the three temperatures. This can be attributed to the fact that the strain rate sensitivity of both prismatic and basal slip systems is at its greatest in this worst case scenario temperature.
采用数字图像相关(DIC)和晶体塑性模拟技术研究了粗晶Ti-6Al合金在高达230℃的3种不同温度下的冷居行为。从大体积晶粒中提取的应变在蠕变过程中进行了DIC测量,并用于校准晶体塑性模型。确定了两种主要滑移体系(基滑移体系和柱滑移体系)的临界分解剪应力(CRSS)随温度的变化规律。在不同的温度下,沿着穿过两个晶粒对(1)“流氓”晶粒对和(2)“非流氓”晶粒对边界的路径的应力被确定。在“流氓”晶粒对中观察到负载脱落,其中在蠕变期间在“硬”晶粒中发现应力增量。在高温下,120℃是最坏的情况,因为这两种晶对晶界处的应力差在三个温度中最大。这可以归因于这样一个事实,即在最坏的情况下,棱柱滑移体系和基滑移体系的应变率敏感性都是最大的。
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引用次数: 0
Learning from Superelasticity Data to Search for Ti-Ni Alloys with Large Elastocaloric Effect 从超弹性数据中学习寻找具有大弹热效应的Ti-Ni合金
Pub Date : 2021-05-12 DOI: 10.2139/ssrn.3844696
Lei Ding, Yumei Zhou, Yangyang Xu, Pengfei Dang, Xiangdong Ding, Jun Sun, T. Lookman, D. Xue
In the present study, the reversible adiabatic temperature change (ΔTad) of shape memory alloys was shown to be proportional to the mechanical work released by the reverse martensitic transformation during unloading (ΔWu). As there exists a considerable amount of data (ΔWu) on superelastic stress-strain measurements in shape memory alloys, the proposed relationship allows us to predict ΔTad without caloric measurements. The estimated ΔTad from the ΔWu of different Ti-Ni alloys shows good linear relationship with the directly measured values. Moreover, following such a design criterion and by tuning of composition and thermo-mechanical treatment, a group of Ti-Ni binary shape memory alloys with a directly measured ΔTad larger than 35 K under tension were achieved. The large ΔTad and ΔWu can be ascribed to the grain refinement and the heterogeneous internal stress fields after the thermo-mechanical treatment, which have enhanced the critical stress of superelasticity and recoverability of martensitic transformation during unloading.
在本研究中,形状记忆合金的可逆绝热温度变化(ΔTad)被证明与卸载过程中反向马氏体相变释放的机械功(ΔWu)成正比。由于存在大量关于形状记忆合金中超弹性应力-应变测量的数据(ΔWu),所提出的关系使我们能够在没有热量测量的情况下预测ΔTad。不同Ti-Ni合金的ΔWu值与直接测量值之间呈现良好的线性关系。此外,按照这样的设计准则,通过调整成分和热处理,获得了一组张力下直接测量的ΔTad大于35 K的Ti-Ni二元形状记忆合金。较大的ΔTad和ΔWu可归因于热处理后的晶粒细化和非均匀内应场,增强了卸荷时的超弹性临界应力和马氏体相变的可恢复性。
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引用次数: 17
Mechanical Properties of Gradient Copper Nano-Gyroid Cellular Structures: A Molecular Dynamics Study 梯度铜纳米陀螺细胞结构的力学性能:分子动力学研究
Pub Date : 2021-04-07 DOI: 10.2139/ssrn.3538809
Rui Dai, Dawei Li, Yunlong Tang
Advanced manufacturing (AM) technologies, such as nanoscale additive manufacturing process, enable the fabrication of nanoscale architected materials which has received great attention due to their prominent properties. However, few studies delve into the functional gradient cellular architecture on nanoscale. This work studied the gradient nano-Gyroid architected material made of copper (Cu) by molecular dynamic (MD) simulations. The result reveals that, unlike homogeneous architecture, gradient Gyroid not only shows novel layer-by-layer deformation behaviour, but also processes significantly better energy absorption ability. Moreover, this deformation behaviour and energy absorption are predictable and designable, which demonstrate its highly programmable potential.
先进制造技术,如纳米级增材制造工艺,使纳米级建筑材料的制造成为可能,由于其突出的性能而受到广泛关注。然而,很少有研究深入研究纳米尺度上的功能梯度细胞结构。本文采用分子动力学(MD)模拟方法研究了由铜(Cu)制成的梯度纳米陀螺结构材料。结果表明,与均匀结构不同,梯度陀螺不仅表现出新颖的逐层变形行为,而且具有明显更好的能量吸收能力。此外,这种变形行为和能量吸收是可预测和可设计的,这表明了其高度可编程的潜力。
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引用次数: 1
Twin-Boundary Assisted Crack Tip Plasticity and Toughening in Lamellar γ-TiAl 片层γ-TiAl双界辅助裂纹尖端塑性与增韧
Pub Date : 2021-02-21 DOI: 10.2139/ssrn.3790079
A. Neogi, R. Janisch
The internal twin-boundaries in lamellar γ-TiAl alloys, namely true-twin (TT), rotational boundary(RB), and pseudo-twin (PT), are known to be effective in strengthening the TiAl microstructures. Nevertheless, for designing microstructures with optimised mechanical properties, a better understanding of the role of these boundaries on fracture behavior is still required. To this end, we study how and to what degree crack advancement is affected by the local lattice orientation and atomic structure at the various twin boundaries. Molecular statics simulations were performed in conjunction with a linear elastic fracture mechanics based analysis, to understand the inter-lamellar and as well as trans-lamellar crack advancement at a TT, RB, and PT interface. The fracture toughness as well as the crack advancement mechanisms of the inter-lamellar cracks depend critically on the propagation direction. For instance, cracks along ⟨11‾2] in the TT, RB, and PT plane always emit dislocations at the crack tip, while the cracks along the opposite direction are brittle in nature. When it comes to trans-lamellar crack advancement, the crack tip shows significant plastic deformation and toughening for all inter-faces. However, at a TT, a brittle crack is able to penetrate through the interface at a higher applied load, and propagates in the adjacent γ′ phase, while in the case of RB and PT, the crack tip is blunted and arrested at or near the boundary, resulting in dislocation emission and crack tip toughening. This suggests that a variation of the sequence of the different rotational boundaries could be a possibility to tune the crack tip plasticity and toughening in lamellar TiAl.
层状γ-TiAl合金的内部孪晶界,即真孪晶界(TT)、旋转孪晶界(RB)和伪孪晶界(PT),对TiAl组织的强化是有效的。然而,为了设计具有最佳力学性能的微观结构,仍然需要更好地了解这些边界在断裂行为中的作用。为此,我们研究了不同孪晶边界处的局部晶格取向和原子结构如何以及在多大程度上影响裂纹扩展。分子静力学模拟与基于线弹性断裂力学的分析相结合,以了解TT、RB和PT界面的片层间和片层间裂纹进展情况。层间裂纹的断裂韧性和裂纹扩展机制与扩展方向密切相关。例如,在TT、RB、PT平面上沿⟨11 * 2]方向的裂缝总是在裂缝尖端发出位错,而沿相反方向的裂缝本质上是脆性的。跨层裂纹扩展时,裂纹尖端各界面均表现出明显的塑性变形和增韧。然而,在高载荷下,脆性裂纹能够穿透界面,并在相邻的γ′相中扩展,而在RB和PT的情况下,裂纹尖端在边界或附近被钝化和阻止,导致位错发射和裂纹尖端增韧。这表明,改变不同旋转边界的顺序可能是调整层状TiAl裂纹尖端塑性和增韧的一种可能性。
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引用次数: 23
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Mechanical Properties & Deformation of Materials eJournal
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