Characterization and Performance of Ultrafine Lead-Free powders

Tan Leng Hin “Adrian”, Pan Wei Chih “Lenz”, Chan Li-san, Lo Yee Ting, Fritzsche Sebastian
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Abstract

With the miniaturization of components in advanced packaging, interconnect requires fine solder joints to be formed. To be able to form small solder joints, solder paste with ultrafine solder particles is required. For ultrafine powder there are important powder characteristics such as particle size distributions (PSD), surface oxide and aspect ratio which need to be considered.A proprietary process technology is used to produce ultrafine SAC305 (Sn-3Ag-0.5Cu) powder with particle size ranging from $2 \mu \mathrm{m}$ to $25 \mu \mathrm{m}$ with tight particle size distributions and high sphericity. Focus will be on new ultrafine powders $(28 \mu \mathrm{m})$ and characterization will be presented for PSD, surface oxide content and aspect ratio. Surface oxide content will be characterized using inert gas fusion infrared technology while particle size distribution is characterized using laser diffraction method.The ultrafine powder was made into solder paste (water soluble) for feasibility studies. Impact of PSD and surface oxide on paste characteristics like solder balling, solder bridging and cold slump will be discussed. Finally, results for printability on ultrafine pitch and solder volume after reflow will be discussed.
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超细无铅粉体的表征与性能
随着先进封装中元件的小型化,互连需要形成精细的焊点。为了能够形成小的焊点,需要具有超细焊料颗粒的锡膏。对于超细粉体,需要考虑粒度分布(PSD)、表面氧化物和长径比等粉体特性。采用自主研发的工艺技术,可制得粒度为$2 \mu \mathrm{m}$ ~ $25 \mu \mathrm{m}$的超细SAC305 (Sn-3Ag-0.5Cu)粉体,粉体粒度分布紧密,球形度高。重点将是新的超细粉末$(28 \mu \ mathm {m})$,并将介绍PSD,表面氧化物含量和纵横比的表征。采用惰性气体融合红外技术对表面氧化物含量进行表征,采用激光衍射法对粒度分布进行表征。将超细粉末制成可溶于水的锡膏,进行可行性研究。将讨论PSD和表面氧化物对膏体特性的影响,如焊锡球团、焊锡桥接和冷坍落度。最后,讨论了回流后超细间距和焊料体积的印刷适性。
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