Thermoelectric properties of layered perovskite-type Nb-doped SrO(SrTiO3)n (n = 1,2) Ruddlesden-Popper phases

Kyu Hyoung Lee, Hiromichi Ohta, K. Koumoto
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引用次数: 3

Abstract

Thermoelectric (TE) properties of natural superlattice Ruddlesden-Popper (RP) phases were measured to elucidate their potential as TE materials, and the origin of the TE properties was discussed from the viewpoint of the shape of the TiO6 octahedron. Compared with the cubic perovskite-type phase Nb-doped SrTiO3, efficient reduction of the lattice thermal conductivity was observed by more than 50 % at room temperature and 30 % at 1000 K. There was a decrease in electrical conductivity owing to the randomly distributed insulating SrO layers in polycrystalline RP phases, and it was found that large TE power can be obtained in conjunction with high symmetry TiO6 octahedra
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层状钙钛矿型铌掺杂SrO(SrTiO3)n (n = 1,2) Ruddlesden-Popper相的热电性能
对天然超晶格Ruddlesden-Popper (RP)相的热电性能进行了测定,以阐明其作为热电材料的潜力,并从TiO6八面体形状的角度讨论了热电性能的来源。与立方钙钛矿型铌掺杂SrTiO3相相比,在室温下晶格导热系数降低了50%以上,在1000 K时降低了30%。在多晶RP相中,随机分布的绝缘SrO层使其电导率降低,并且发现高对称性的TiO6八面体可以获得较大的TE功率
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